Sunflower Shell Biocomposite Formaldehyde Reduction

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Solution Overview

Problem

Current biocomposites derived from wood-based materials face challenges such as high formaldehyde emission, density above 1.0 g/cm³, and lack of thermoplastic behavior, which hinder their use in lightweight, CO₂-storing applications, especially in automotive and indoor settings where low formaldehyde emission and thermoplastic properties are required.

Innovation Solution

A process involving the use of sunflower seed shells as a primary biological substrate, combined with a thermoplastic polymer that does not contain formaldehyde, to create a thermoformable and/or embossable particle/polymer biocomposite, which can be produced at low cost and with high sunflower seed shell content, optionally incorporating fine wood chips for layered structures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If standard wood-based boards (particle boards, MDF, OSB) bonded with formaldehyde-containing resins are used, then mechanical strength and structural stability are achieved, but formaldehyde emission increases and thermoplastic behavior is lost

Engineering Contradiction:
Improvemechanical strengthVSAvoidformaldehyde emission
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the bonding system by replacing formaldehyde-containing resins (UF, PF, MUF) with formaldehyde-free thermoplastic polymers. This parameter change eliminates the harmful formaldehyde emission while maintaining the structural integrity through alternative bonding mechanisms that do not rely on formaldehyde-based chemistry.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite materials combining sunflower seed shells with thermoplastic polymers to form particle/polymer biocomposites. This composite approach allows the integration of renewable agricultural waste with polymer bonding agents that provide structural strength without formaldehyde, achieving both environmental and mechanical performance goals.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If standard wood-based boards are used, then structural stability is achieved, but density increases above 1.0 g/cm³ and thermoplastic behavior is lost

Engineering Contradiction:
Improvestructural stabilityVSAvoiddensity
Core Design Contradiction:
Stability of the object's compositionVSWeight of moving object

Solution Approach 1:

The patent changes the physical and chemical parameters of the composite material by using thermoplastic polymers with specific melting ranges and processing temperatures. This allows the material to be processed into lightweight structures with density below 1.0 g/cm³ while maintaining structural stability through the thermoplastic bonding mechanism that provides both strength and formability.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If sunflower seed shells are used as a by-product, then CO2 storage potential and formaldehyde reduction are achieved, but processing complexity and energy input increase

Engineering Contradiction:
Improveformaldehyde contentVSAvoidprocessing complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent utilizes sunflower seed shells as a low-cost, readily available agricultural by-product that would otherwise be discarded. By incorporating this waste material directly into the composite formulation, the process avoids the need for expensive specialized processing equipment while achieving formaldehyde reduction and CO2 storage benefits through the natural properties of the sunflower seed shell material.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Object-generated harmful factors

If thermoplastic polymers are used instead of formaldehyde-containing resins, then formaldehyde emission is reduced and thermoplastic behavior is achieved, but manufacturing process complexity increases

Engineering Contradiction:
Improveformaldehyde emissionVSAvoidmanufacturing process simplicity
Core Design Contradiction:
Object-generated harmful factorsVSEase of manufacture

Solution Approach 1:

The patent changes the processing parameters by utilizing the melting and cooling cycles of thermoplastic polymers to achieve bonding and shaping. This parameter-based approach allows for simplified manufacturing processes where the thermoplastic material is heated to melt, mixed with sunflower seed shells, and then cooled to bond, eliminating the need for complex formaldehyde-curing chemistry while maintaining ease of production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting biocomposites exhibit low formaldehyde emission, a density below 1.0 g/cm³, and thermoplastic behavior, enabling their use in lightweight applications for CO₂ storage and indoor components like furniture and building elements while maintaining mechanical stability and thermal dimensional stability.

Implementation Method 1

the substrate S/polymer P mixture is converted into a particle layer, thereafter the resulting structure is compressed at a temperature greater than or equal to the glass transition temperature of the polymer P [TgP] to form a thermoformable and/or embossable particle/polymer composite

Methodology Applied
Scientific EffectGlass transition: Phase Change

Data Source

PatentEP4032943A1Manufacturing process for components from sunflower seed shells, particle/polymer biocomposites, moldings and laminates comprising sunflower seed shells, and their use
Publication Date: 2022.07.27 ECOBRAIN AG
  • EP4032943A1 patent drawingFigure 1~4
  • EP4032943A1 patent drawingFigure 5~6
  • EP4032943A1 patent drawingFigure 7~8

AI summary

Disclosed is a process for producing a thermoformable and/or embossable particle/polymer biocomposite using a particulate biological substrate S and a polymer P, characterized in that (i) a substrate S and the polymer P are homogeneously mixed, then (ii) the substrate S/polymer P mixture is converted into a particle layer, thereafter (iii) the resulting structure is compressed at a temperature greater than or equal to the glass transition temperature of the polymer P [TgP] to form a thermoformable and/or embossable particle/polymer composite, where (a) the substrate S comprises sunflower seed shells; and (b) the polymer P is thermoplastic and has a TgP ≥ 20 °C measured according to DIN EN ISO 11357-2 (2013-09). Furthermore, a process for the manufacturing of a particle/polymer molding using said semi-finished biocomposite as a starting material, a particle/polymer molding and its use as an element in buildings or in furniture are disclosed.