Superabsorbent Bicomponent Fiber Core-Sheath Structure

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Solution Overview

Problem

Existing superabsorbent bicomponent fibers face challenges with mechanical stability and spinning behavior, and there is a need for improved water absorbency and nozzle life.

Innovation Solution

The development of a superabsorbent bicomponent fiber with a core-sheath structure, where high-melting thermoplastic polymers like polyethylene terephthalate form the core and a polyolefin-based SAP-rich sheath, optimized through coextrusion and processing to achieve balanced mechanical stability and water absorbency, with SAP ground to a specific particle size for efficient spinning.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If SAP content in the sheath is increased to improve water absorbency, then water absorbency is improved, but mechanical stability deteriorates

Engineering Contradiction:
ImproveSAP contentVSAvoidmechanical stability
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The fiber is divided into two distinct components: a core made of high-melting thermoplastic polymer providing mechanical strength, and a sheath made of low-melting thermoplastic polymer containing SAP for water absorbency. This segmentation allows each component to fulfill its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the bicomponent fiber have different properties: the core region provides mechanical stability with high-melting polymer, while the sheath region provides water absorbency with SAP-containing low-melting polymer. This local differentiation resolves the contradiction by assigning specific functions to specific regions.

Inventive Principle:
Principle #3Local quality

2Quantity of substance

If SAP particle size is reduced to improve water absorbency, then water absorbency is improved, but spinning behavior deteriorates

Engineering Contradiction:
Improvewater absorbencyVSAvoidspinning behavior
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The SAP particle size is controlled within a specific range (1-10 μm, preferably 2-5 μm) to optimize both water absorbency and spinning behavior. This parameter optimization resolves the contradiction by finding the optimal balance point where both requirements are satisfied.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If SAP content is increased to improve water absorbency, then water absorbency is improved, but nozzle life deteriorates

Engineering Contradiction:
Improvewater absorbencyVSAvoidnozzle life
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The low-melting thermoplastic polymer in the sheath has a melting point at least 20°C lower than the core polymer, enabling controlled melting and bonding during spinning. This temperature parameter control allows SAP to be effectively incorporated while maintaining nozzle integrity and extending nozzle life.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The sheath is formed as a composite material of low-melting thermoplastic polymer and SAP, where the polymer matrix provides structural integrity during processing while the SAP particles provide water absorbency. This composite structure allows high SAP content without compromising nozzle life.

Inventive Principle:
Principle #40Composite materials

4Strength

If core-sheath structure is used to improve mechanical stability, then mechanical stability is improved, but production complexity increases

Engineering Contradiction:
Improvemechanical stabilityVSAvoidproduction complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The coextrusion process divides the fiber production into two separate polymer streams that are extruded simultaneously to form core and sheath structures. This segmentation approach achieves complex functionality through a systematic division of the manufacturing process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The core-sheath bicomponent structure serves multiple functions simultaneously: the core provides mechanical strength and structural integrity, while the sheath provides water absorbency through SAP. This multi-functionality is achieved through a single integrated fiber structure, reducing the need for separate components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting fibers exhibit enhanced mechanical stability and water absorbency, enabling the production of robust and effective superabsorbent textile fabrics suitable for hygiene, medical, and packaging applications, with the ability to prevent clogging in sewage systems due to controlled swelling.

Implementation Method 1

The SAP used according to the invention should preferably have sufficient thermal stability with regard to the melt spinning process

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

the melting point of the thermoplastic contained in component A being at least 20° C. higher than the melting point of the thermoplastic contained in component B

Methodology Applied
Scientific EffectMelting point difference: Melting

Implementation Method 3

The bicomponent filaments are produced by coextrusion of the two aforementioned polymer mixtures

Methodology Applied
Scientific EffectCoextrusion: Extrusion

Data Source

PatentEP2334852B1Superabsorbent bi-component fiber
Publication Date: 2016.03.30 TREVIRA GMBH & CO KG

AI summary

A superabsorbent bi-component fiber, wherein component A is at least one thermoplastic polymer and component B is a compound selected from at least one thermoplastic base polymer and at least one superabsorbent polymer (SAP), and also a method for production thereof are described.  The melting point of the thermoplastic contained in component A is at least 20°C higher than the melting point of the thermoplastic contained in component B, the average grain size of the SAP is 0.5 to 10 µm and the compound has an SAP-fraction of 0.5 to 40 wt%.  The bi-component fiber can be used to produce superabsorbent textile fabrics which are used in particular in the field of hygiene and medicine.