Superabsorbent Foam Composite for Hygiene Articles

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Solution Overview

Problem

Feminine hygiene absorbent articles with superabsorbent foams face challenges in achieving good absorbing, retaining, and conducting properties for aqueous fluids while maintaining stability, especially in the wet state, and require improved production efficiency and non-shrinkage upon drying.

Innovation Solution

A feminine hygiene absorbent article comprising a superabsorbent foam layer and a synthetic fiber web layer, where the foam is created by foaming an aqueous mixture of monoethylenically unsaturated monomers with acid groups, crosslinkers, and surfactants, and polymerized in the presence of the web, resulting in a composite that swells one-dimensionally and does not shrink upon drying.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If superabsorbent foams are used to absorb body fluids, then absorption and retention capabilities are improved, but mechanical stability and handling properties deteriorate

Engineering Contradiction:
Improveabsorption capacityVSAvoidmechanical stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent combines superabsorbent polymer foam with a synthetic fiber web to create a composite structure. The foam provides absorption capacity while the web provides mechanical stability and handling properties, resolving the contradiction between absorption performance and mechanical reliability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The superabsorbent foam layer utilizes a porous structure to enable high fluid absorption capacity. The controlled porosity allows rapid fluid uptake while the foam matrix maintains structural integrity when combined with the supporting web

Inventive Principle:
Principle #31Porous materials

2Productivity

If foam is produced by foaming aqueous mixtures and polymerizing, then production efficiency is improved, but dimensional stability during drying deteriorates (shrinkage occurs)

Engineering Contradiction:
Improveproduction efficiencyVSAvoiddimensional stability
Core Design Contradiction:
ProductivityVSShape

Solution Approach 1:

The patent modifies the polymerization parameters and foam composition to control the crosslinking density and cell structure. By adjusting these parameters, the foam maintains dimensional stability during drying while preserving production efficiency through the continuous foaming-polymerization process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite structure of foam embedded in a synthetic web prevents shrinkage during drying. The web acts as a structural framework that constrains the foam cells, maintaining dimensional stability while allowing the foam to retain its absorption functionality

Inventive Principle:
Principle #40Composite materials

3Strength

If crosslinking is increased to enhance wet strength, then strength in wet state is improved, but processing complexity and production difficulty increase

Engineering Contradiction:
Improvewet strengthVSAvoidprocessing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies crosslinking locally at the interface between the foam and the synthetic web, rather than throughout the entire foam structure. This localized crosslinking enhances wet strength at the critical bonding region while keeping the bulk foam processable and reducing overall processing complexity

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides absorbent articles with enhanced absorption and retention capabilities for body fluids, maintaining mechanical stability and ease of production, with improved handling and environmental compatibility.

Implementation Method 1

They are produced for example by foaming a polymerizable aqueous mixture comprising not less than 50 mol % neutralized acid-functional monoethylenically unsaturated monomers, crosslinkers and at least one surfactant

Methodology Applied
Scientific EffectFoaming: Foam

Implementation Method 2

The foams are used for example in hygiene articles to acquire, distribute and store body fluids

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

polymerizing the foamed mixture

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS9149556B2Feminine hygiene absorbent articles comprising water-absorbing composites
Publication Date: 2015.10.06 PROCTER & GAMBLE CO
  • US9149556B2 patent drawing

AI summary

This invention relates to a feminine hygiene absorbent article comprising water-absorbing composites obtainable by foaming an aqueous mixture comprising at least one monoethylenically unsaturated monomer bearing acid groups, at least one crosslinker, at least one initiator and at least one surfactant, contacting the foam obtained with at least one web of synthetic fibers and polymerizing, to the composites themselves and to their use for absorbing aqueous fluids.