Superconducting Alloy Interface Oxidation Prevention

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Solution Overview

Problem

Superconducting quantum circuits face challenges in maintaining low error rates and reliability due to oxidation and surface contamination, which affect qubit coherence and signal integrity, as conventional integrated circuit techniques are not effective in protecting these unique interfaces.

Innovation Solution

A superconductor device is fabricated with a niobium (Nb) first metal layer and an aluminum (Al) second metal layer, forming a niobium aluminide (Al3Nb) alloy without an oxide layer between them, and an electrode is deposited on top, with the second metal layer applied before exposure to air or after cleaning to prevent oxidation, and annealed to create an aligned lattice orientation for improved electrical path and protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional integrated circuit techniques are used to fabricate superconducting quantum circuits, then manufacturing simplicity is maintained, but oxidation and surface contamination occur at metal layer interfaces, degrading qubit coherence and signal integrity

Engineering Contradiction:
Improvequbit coherence and signal integrityVSAvoidoxidation and surface contamination
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by depositing the aluminum layer immediately after the niobium layer while both are still in the vacuum chamber, preventing oxidation before it can occur. This in-situ deposition sequence ensures the niobium surface is protected from atmospheric exposure during the critical interface formation stage

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes the vacuum environment as an inert atmosphere during the metal layer deposition process. By maintaining vacuum conditions from niobium deposition through aluminum deposition and alloy formation, the process prevents oxidation and contamination that would occur in atmospheric conditions

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Reliability

If a second metal layer is deposited on the first metal layer to form a superconducting alloy, then electrical path and protection are improved, but oxide layers may form at the interface, affecting device performance

Engineering Contradiction:
Improveelectrical path qualityVSAvoidinterface cleanliness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The aluminum layer is deposited preliminarily on the niobium surface while still in vacuum, creating a fresh interface before any oxidation can occur. This preliminary deposition protects the niobium surface and ensures clean alloy formation

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The process maintains continuous vacuum conditions throughout the entire sequence from niobium deposition to aluminum deposition and alloy formation. This continuous protective environment ensures the interface remains free from oxidation and contamination throughout the critical fabrication steps

Inventive Principle:
Principle #20Continuity of useful action

3Ease of operation

If the first metal layer is exposed to air after deposition, then handling and processing become easier, but oxidation occurs on the surface, degrading superconducting performance

Engineering Contradiction:
Improvehandling convenienceVSAvoidsurface quality
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The aluminum layer is deposited preliminarily on the niobium surface while still in vacuum, creating a protective barrier before air exposure. This preliminary protective action prevents subsequent oxidation when the device is handled or processed in atmospheric conditions

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The aluminum layer serves as an intermediary protective barrier between the niobium surface and the atmospheric environment. This intermediate layer prevents direct contact between oxygen and the niobium, eliminating oxidation while allowing subsequent handling and processing

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the decoherence and signal integrity of superconducting qubits by eliminating residual oxides and surface contamination, leading to more reliable and consistent performance in quantum computing.

Implementation Method 1

annealed to create an aligned lattice orientation for improved electrical path and protection

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

forming a niobium aluminide (Al3Nb) alloy between them

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

the superconducting alloy is operative to protect the first metal layer from oxidation or contamination that could affect a performance of the superconductor device

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Implementation Method 4

maintaining the superconductor device in a vacuum between a deposition of the first metal layer and a deposition of the second metal layer

Methodology Applied
Scientific EffectVacuum: Vacuum

Data Source

PatentEP4186112B1Superconducting structure and device surface termination with alloy and fabrication thereof
Publication Date: 2024.09.25 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • EP4186112B1 patent drawingFigure 1A~1B
  • EP4186112B1 patent drawingFigure 2
  • EP4186112B1 patent drawingFigure 3A~3D

AI summary

A method of fabricating a superconductor device includes providing a first metal layer on top of the substrate. An oxidation of a top surface of the first metal layer is rejected. A second metal layer is deposited on top of the first metal layer. A superconducting alloy of the first metal layer and the second metal layer is created between the first metal layerand the second metal layer. There is no oxide layer between the superconducting alloy and the first metal layer.