Superconducting Device Bridge Layer Junction

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Solution Overview

Problem

Reliably forming a junction between normal and superconducting parts in quantum interference devices is challenging due to the rapid oxidation of aluminum, which prevents electrical contact when deposited on niobium, limiting material choices and increasing manufacturing costs.

Innovation Solution

Incorporating a bridge layer of conductive materials like gold, silver, or copper between the superconducting and normal layers, allowing for flexible deposition order and material selection, and using titanium as a normal conductor with an initial thickness greater than its passivation depth to maintain conductivity, while oxidizing to increase resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If aluminum is used as the normal conductor material due to its ease of manufacture and passivation properties, then ease of manufacture is improved, but reliability deteriorates because rapid oxidation prevents electrical contact when deposited on niobium

Engineering Contradiction:
Improveease of manufactureVSAvoidreliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A bridge layer of titanium is introduced between the aluminum normal conductor and the niobium superconductor. This intermediary layer prevents direct oxidation of the aluminum-niobium interface while maintaining electrical conductivity, thus resolving the contradiction between ease of manufacture and reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The junction is constructed as a composite structure with multiple layers: niobium superconductor, titanium bridge layer, and aluminum normal conductor. This composite approach combines the advantages of each material while mitigating their individual drawbacks, achieving both manufacturability and reliable electrical contact

Inventive Principle:
Principle #40Composite materials

2Reliability

If the deposition order is reversed to prevent oxidation issues, then reliability is improved, but ease of manufacture deteriorates because the native oxide layer on aluminum prevents electrical contact

Engineering Contradiction:
ImprovereliabilityVSAvoidease of manufacture
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The titanium bridge layer serves as a protective intermediary that allows aluminum to be deposited first without direct exposure to niobium. The titanium layer prevents oxidation at the critical interface while maintaining the preferred deposition sequence for manufacturability

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If material choices are limited to avoid oxidation problems, then reliability is improved, but adaptability deteriorates because fewer material combinations are available

Engineering Contradiction:
ImprovereliabilityVSAvoidadaptability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The titanium bridge layer provides a universal solution that works with various superconductor-normal conductor material combinations. It enables reliable junction formation regardless of the specific materials used, thus improving adaptability while maintaining reliability

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The titanium intermediary layer decouples the material selection constraints, allowing independent optimization of superconductor and normal conductor materials without worrying about direct compatibility issues, thereby enhancing adaptability

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If additional bridge layers are added to ensure reliable connections, then reliability is improved, but device complexity increases

Engineering Contradiction:
ImprovereliabilityVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The titanium bridge layer is applied locally only at the critical junction areas where superconductor-normal conductor interfaces occur. This localized approach ensures reliable connections only where needed, minimizing the increase in overall device complexity while maintaining reliability

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the reliability and cost-effectiveness of quantum interference device manufacturing by enabling reliable electrical connections and improved device performance through increased resistance, allowing for the use of various materials and reducing manufacturing complexities.

Implementation Method 1

Incorporating a bridge layer of conductive materials like gold, silver, or copper between the superconducting and normal layers

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

using titanium as a normal conductor with an initial thickness greater than its passivation depth to maintain conductivity, while oxidizing to increase resistance

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

The flux through the superconducting loop 51 affects the phase difference between interfaces 53 and 54 and hence causes quantum interference between the electrons reflected by the two boundaries

Methodology Applied
Scientific EffectQuantum interference: Interference

Implementation Method 4

When a current is passed across the interferometer 55, quasiparticles are reflected from the normal:superconducting interfaces 53, 54 (Andreev reflection)

Methodology Applied
Scientific EffectAndreev reflection:

Data Source

PatentEP3345009B1Superconducting device and method of manufacturing a superconducting device
Publication Date: 2022.09.14 ROYAL HOLLOWAY & BEDFORD NEW COLLEGE
  • EP3345009B1 patent drawingFigure 1~3
  • EP3345009B1 patent drawingFigure 4~6
  • EP3345009B1 patent drawingFigure 7~8

AI summary

A quantum interference device comprising a superconducting loop interrupted by a normal conductor segment, and an interferometer connected to the normal conductor segment wherein the superconducting loop comprises a plurality of turns. The turns can be a plurality of adjacent lobes. A coil can be located within a lobe of the superconducting loop. Optionally a bridge layer (e.g. of gold) is formed above the substrate to make an electrical contact between a superconducting layer (e.g. of niobium) formed above the bridge layer and a normal conducting layer (e.g. of titanium) formed above the bridge layer. The bridge layer allows the device to be formed of superconducting and normal conducting materials that are otherwise incompatible. A titanium normal conducting layer can be allowed to oxidise over a period of years.