Oxide Superconducting Wire Grain Orientation for Low Interlayer Resistance

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Solution Overview

Problem

Oxide superconducting wires experience increased connection resistance and joule heat at connection points due to soldering, and there is a challenge in bypassing current during quenching with reduced interlayer resistance between the superconducting and protective layers.

Innovation Solution

The superconducting layer is configured with a specific proportion of a-axis oriented grains, ranging from 4.1% to 11.9%, to reduce interlayer resistance, and in some cases, two superconducting layers with different a-axis oriented grain ratios are used to further enhance this effect.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If oxide superconducting wires are solder-connected to produce long wires, then wire length is increased, but connection resistance at the connection part increases and joule heat is generated

Engineering Contradiction:
Improvewire lengthVSAvoidconnection resistance
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The patent changes the crystallographic orientation parameters of the superconducting layer by controlling the a-axis oriented grain ratio to be 10% or more, which fundamentally alters the electrical properties at the interface between the superconducting layer and protective layer, thereby reducing contact resistance and improving solder connection reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure within the superconducting layer by combining c-axis oriented grains (for high critical current density) with a-axis oriented grains (for low contact resistance), achieving a balance between current carrying capacity and connection quality

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If connection resistance increases, then wire length can be extended through soldering, but bypass current flow during quenching is reduced

Engineering Contradiction:
Improvewire lengthVSAvoidbypass current flow
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

By adjusting the a-axis oriented grain ratio to 10% or more, the patent modifies the interfacial resistance characteristics between the superconducting layer and protective layer, ensuring adequate bypass current pathways during quenching events while maintaining extended wire length capability

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the proportion of a-axis oriented grains is increased to reduce interlayer resistance, then contact resistance decreases, but critical current density may be affected

Engineering Contradiction:
Improveinterlayer resistanceVSAvoidcritical current density
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent optimizes the a-axis oriented grain ratio to be 10% or more but not exceeding a certain threshold, creating an optimal balance point where contact resistance is sufficiently reduced while critical current density remains above minimum required levels

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates local regions with different grain orientations within the superconducting layer, where a-axis oriented grains are concentrated at the interface with the protective layer to reduce contact resistance, while c-axis oriented grains dominate the bulk to maintain high critical current density

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in reduced interlayer resistance and ensures a high critical current density in the longitudinal direction of the superconducting wire, allowing for the production of long wires with lower connection resistance.

Implementation Method 1

a-axis oriented grains having the a-axis oriented in a direction perpendicular to the main surface of the substrate have an effect on an interlayer resistance between the superconducting layer and the protective layer

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

oxide superconducting wire having a reduced interlayer resistance

Methodology Applied
Scientific EffectSuperconductivity: Superconductivity

Data Source

PatentEP4219401B1Oxide superconducting wire
Publication Date: 2026.04.01 FUJIKURA LTD
  • EP4219401B1 patent drawingFigure 1~2
  • EP4219401B1 patent drawingFigure 3

AI summary

An oxide superconducting wire according to the invention includes a substrate having a main surface, a superconducting layer provided above the substrate and formed of a rare-earth high-temperature superconductor, and a protective layer provided on the superconducting layer and in contact with the superconducting layer. The superconducting layer includes a-axis oriented grains having an a-axis oriented in a direction perpendicular to the main surface of the substrate. An a-axis oriented grain ratio expressing a proportion of the a-axis oriented grains to an entirety of crystal grains forming the superconducting layer is in a range of 4.1 to 11.9%.