Superheater Protective Shell for Corrosion Control

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Solution Overview

Problem

Superheaters in steam boilers, particularly those using waste and biomass fuels, face significant corrosion issues due to high chlorine and alkali content, leading to fouling and reduced operational efficiency, as existing materials struggle to withstand both high temperatures and pressures while maintaining a surface temperature below the melting point of corrosive compounds.

Innovation Solution

The solution involves maintaining the surface temperature of the superheater above the upper critical temperature (Tk2), where corrosive compounds are in a gaseous form, using a protective shell that isolates the steam pipe from corrosive gases, and employing an insulator to control heat conduction, allowing for higher superheating temperatures without deposit formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the surface temperature of the superheater is kept below the melting temperature of corrosive compounds, then corrosion is reduced, but the superheating temperature is limited and operational economy decreases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidelectricity production
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The superheater structure is divided into two distinct temperature zones: the surface layer maintains low temperature (below melting point of corrosive compounds) for corrosion protection, while the interior achieves high temperature (above critical temperature Tk2) for efficient steam superheating and electricity production. This segmentation allows simultaneous optimization of both corrosion resistance and productivity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different parts of the superheater material have different temperature characteristics - the outer surface layer is designed to remain cool to prevent corrosion, while the inner core reaches high temperatures for thermal processing. This local quality differentiation enables the system to simultaneously achieve corrosion protection and high-temperature efficiency.

Inventive Principle:
Principle #3Local quality

2Reliability

If expensive corrosion-resistant materials are used to withstand high temperature and pressure, then reliability improves, but manufacturing cost increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmaterial cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention changes the temperature parameter distribution within the material - keeping the surface temperature below the critical melting point Tk1 of corrosive compounds while allowing the interior to reach high temperatures. This parameter change enables the use of less expensive materials that would otherwise be unsuitable for high-temperature corrosion environments, significantly reducing manufacturing costs while maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the surface temperature is raised above the upper critical temperature Tk2, then smelt formation is prevented and corrosion decreases, but material pressure resistance requirements increase

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmaterial durability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The superheater structure segments the temperature exposure - the surface layer experiences low temperatures for corrosion protection, while the interior experiences high temperatures for efficient operation. This segmentation allows the surface material to focus on corrosion resistance while the interior structure handles the mechanical strength requirements under high temperature and pressure conditions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention employs a composite structure where the outer surface layer and interior core have different functional requirements - the surface layer is optimized for corrosion resistance at low temperatures, while the interior is designed for high-temperature strength and pressure resistance. This composite approach allows optimal material selection for each zone, achieving both corrosion protection and mechanical durability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces corrosion and fouling, enabling higher superheating temperatures, increased electricity production, and cost-effective maintenance by using less expensive materials that do not require pressure resistance, thus improving operational efficiency and flexibility in fuel usage.

Implementation Method 1

employing an insulator to control heat conduction

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

employing an insulator to control heat conduction

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentUS9371987B2Structure of a super heater
Publication Date: 2016.06.21 VALMET TECH OY
  • US9371987B2 patent drawing
  • US9371987B2 patent drawing
  • US9371987B2 patent drawing

AI summary

A method for reducing corrosion of a superheater of a steam boiler. The superheater includes a superheater piping. The superheating piping includes a steam pipe where the steam to be superheated is directed. The steam pipe is separated by a protective shell having a surface settling in the flue gas space has a temperature that rises above an upper critical temperature, above which temperature in the flue gas space the compounds from the fuel are substantially in a gaseous form. A superheater of a steam boiler and a circulating fluidized bed boiler.