3D Printing Support Layer Decomposition for Impurity Control

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Solution Overview

Problem

Existing methods for producing three-dimensional shaped articles using a support layer often result in impurities from the support layer being incorporated into the constituent layer, particularly in low-density structures, due to the incorporation of impurities during the heating process.

Innovation Solution

A method involving the formation of layers using compositions with specific powders and binders, where the decomposition points and sintering temperatures are carefully controlled to remove impurities from the support layer, ensuring that the sintering temperature of the constituent material powder is higher than the decomposition point of the support layer materials, thereby preventing impurities from being incorporated into the final product.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a support layer is used to support the constituent layer during production, then the structural stability during manufacturing is improved, but impurities from the support layer are incorporated into the constituent layer

Engineering Contradiction:
Improvestructural stabilityVSAvoidimpurity incorporation
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The harmful support layer material is extracted and removed through selective decomposition. The support layer uses a powder with decomposition point Ts, which is lower than the sintering temperature Tc of the constituent material. During heating, the support layer powder decomposes and is removed, leaving only the sintered constituent material without impurity incorporation.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the thermal parameters of the support layer material by selecting a powder with decomposition point Ts that is lower than the sintering temperature Tc of the constituent material. This parameter difference enables selective removal of the support layer through controlled heating, resolving the contradiction between structural stability during manufacturing and impurity prevention in the final product.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the sintering temperature is increased to densify the constituent material, then the density and strength of the final product are improved, but impurities from the support layer are more likely to be incorporated

Engineering Contradiction:
Improvedensity controlVSAvoidimpurity incorporation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The support layer material is extracted through selective decomposition at temperature Ts, which is lower than the sintering temperature Tc. This allows the constituent material to be sintered at high temperature Tc for densification while the support layer material decomposes and is removed, preventing impurity incorporation even at high sintering temperatures.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the decomposition temperature parameter Ts of the support layer powder to be lower than the sintering temperature Tc of the constituent material. This parameter differentiation enables the constituent material to achieve high density through sintering at Tc while the support layer material decomposes and is removed, preventing impurity incorporation.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If the support layer material is removed at lower temperatures, then impurity incorporation is reduced, but the structural integrity during heating may be compromised

Engineering Contradiction:
Improveimpurity incorporationVSAvoidstructural integrity
Core Design Contradiction:
Object-generated harmful factorsVSStrength

Solution Approach 1:

The support layer material is designed to decompose at temperature Ts before the sintering temperature Tc of the constituent material. This preliminary decomposition action removes the support layer material while the constituent material remains intact and maintains structural integrity, preventing impurity incorporation without compromising strength.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the decomposition temperature Ts of the support layer powder to be lower than the sintering temperature Tc of the constituent material. This parameter differentiation enables the support layer to be removed at temperature Ts while the constituent material maintains its structural integrity until sintering at Tc, resolving the contradiction between impurity removal and structural strength.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively prevents impurities from the support layer from being incorporated into the three-dimensional shaped article, maintaining the integrity and purity of the final product by carefully managing the thermal processing conditions.

Implementation Method 1

a decomposition point of the first powder is higher than decomposition points of the binder of the first layer and the binder of the second layer

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

sintering the constituent material powder by heating the stack containing the first layer and the second layer

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS11534964B2Method for producing three-dimensional shaped article
Publication Date: 2022.12.27 SEIKO EPSON CORP
  • US11534964B2 patent drawing
  • US11534964B2 patent drawing
  • US11534964B2 patent drawing

AI summary

Provided is a method which includes a first layer formation step of forming a first layer by using a first composition that contains a constituent material powder, a first powder, and a binder of a three-dimensional shaped article; a second layer formation step of forming a second layer by using a second composition that contains a second powder and a binder; a degreasing step of a stack containing the first layer and the second layer; and a sintering step of the stack, a decomposition point of the first powder is higher than decomposition points of the binder of the first layer and the binder of the second layer, a decomposition point of the second powder is higher than the decomposition point of the first powder, and a sintering temperature of the constituent material powder is higher than the decomposition point of the second powder.