Supramolecular Compounds Single 4H-Unit Low Melt Viscosity

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Solution Overview

Problem

Existing supramolecular compounds with quadruple hydrogen bonding units (4H-units) often require multiple units per molecule to achieve polymeric properties, leading to high molecular weights and melt viscosities, which limit their processing efficiency and application in coatings, adhesives, and inks.

Innovation Solution

Development of supramolecular compounds with a single 4H-unit per molecule, using apolar low molecular weight compounds with melting points below 45°C, allowing for the formation of polymeric properties such as film-forming and ductility while maintaining low melt viscosity, achieved through reactions with 4H-units or linker molecules.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If multiple 4H-units are used per molecule to achieve polymeric properties, then film-forming and ductility are improved, but melt viscosity increases and processing efficiency decreases

Engineering Contradiction:
Improvepolymeric properties (film-forming and ductility)VSAvoidprocessing efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent changes the molecular weight parameter and the number of 4H-units per molecule from multiple to single, while adjusting the apolar compound structure to maintain polymeric properties with lower melt viscosity, enabling efficient processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure combining a single 4H-unit with specific apolar low molecular weight compounds (melting point below 45°C), achieving a balance between polymeric properties and processability through the synergistic combination of these components

Inventive Principle:
Principle #40Composite materials

2Strength

If multiple 4H-units are used per molecule to achieve polymeric properties, then film-forming and ductility are improved, but molecular weight increases

Engineering Contradiction:
Improvepolymeric properties (film-forming and ductility)VSAvoidmolecular weight
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The patent changes the molecular weight parameter by using low molecular weight apolar compounds (80-1500 amu) with a single 4H-unit, achieving polymeric properties through supramolecular assembly rather than high molecular weight covalent structures

Inventive Principle:
Principle #35Parameter changes

3Productivity

If low molecular weight apolar compounds with melting point below 45°C are used, then melt viscosity is reduced and processing is improved, but polymeric properties may be compromised

Engineering Contradiction:
Improveprocessing efficiencyVSAvoidpolymeric properties (film-forming and ductility)
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent uses low molecular weight apolar compounds that are simple and easy to process, sacrificing the need for complex high molecular weight structures while achieving the desired properties through supramolecular interactions of single 4H-units

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates a composite system where the single 4H-unit compound works synergistically with the apolar low molecular weight compound to achieve both low melt viscosity for processing and polymeric properties for performance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting compounds exhibit polymeric properties like good film-forming and ductility with low melt viscosity, enabling easier processing and broader application in coatings, adhesives, and inks without the need for high molecular weights.

Implementation Method 1

supramolecular compounds comprising only one quadruple hydrogen bonding unit per molecule... physical interactions between different supramolecular compounds originate from multiple hydrogen bonding interactions (supramolecular interactions)

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Data Source

PatentEP2310376B1High flow supramolecular compounds
Publication Date: 2014.11.05 SUPRAPOLIX
  • EP2310376B1 patent drawing
  • EP2310376B1 patent drawing
  • EP2310376B1 patent drawing

AI summary

The present invention relates to a supramolecular compound comprising a low molecular weight, apolar compound, said low molecular weight, apolar compound having a melting point of below 45°C, a molecular weight of about 80 to about 1500 amu and a HLB-valueof lower than 8, said low molecular weight, apolar compound bearing a single 4H-unit per molecule. The supramolecular compound according to the present invention may be used in coating, ink, toner, resin, lacquer, adhesive or glue compositions.