Surface-Active Metal Complexes for Pollutant Adsorption

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Solution Overview

Problem

Existing metal salts used for binding pollutants and odor-forming substances are typically water-insoluble and lack surface-active properties, limiting their effectiveness in chemical binding and adsorption applications.

Innovation Solution

Complexed metal salts are formed by combining water-soluble ligands with bifunctional or polyfunctional complexing agents, creating water-soluble and surface-active compounds that can be deposited on carrier materials for enhanced pollutant and odor binding capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If water-insoluble metal salts are used for binding pollutants, then they can provide deodorizing effect and chemical binding capability, but they lack water solubility and surface-active properties which limits their effectiveness

Engineering Contradiction:
Improvedeodorizing effect and chemical binding capabilityVSAvoidwater solubility and surface activity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent creates composite structures by combining water-insoluble metal salts with water-soluble surfactants to form complexed metal salts. This composite approach allows the material to simultaneously possess the deodorizing capability of the metal salt and the water solubility/surface activity of the surfactant, resolving the contradiction between reliability and ease of operation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical parameters of the metal salt by forming complexes with ligands and complexing agents. This transformation modifies the solubility and surface activity parameters while preserving the core deodorizing function, allowing the material to meet both requirements of effectiveness and ease of use.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If complexed metal salts are formed with water-soluble ligands and complexing agents, then water solubility and surface activity are improved, but the complexity of the chemical composition increases

Engineering Contradiction:
Improvewater solubility and surface activityVSAvoidchemical composition complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent segments the complexed metal salt into distinct functional components: the metal salt core providing deodorizing activity, ligands providing structural framework, and complexing agents providing water solubility. This segmentation allows each component to be optimized independently while maintaining overall functionality, managing composition complexity effectively.

Inventive Principle:
Principle #1Segmentation

3Reliability

If metal salts are deposited on carrier materials, then adsorption capability for pollutants is enhanced, but the manufacturing process becomes more complex

Engineering Contradiction:
Improveadsorption capabilityVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies complexed metal salts to carrier materials through straightforward deposition processes. The complexed metal salt is prepared in advance with all necessary solubility and activity properties, allowing simple subsequent application to the carrier without requiring complex in-situ formation processes, thus enhancing adsorption capability while maintaining manufacturing simplicity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting complexed metal salts demonstrate improved water solubility and surface activity, enabling effective chemical binding and adsorption of pollutants and odor-forming substances, including those with electron donor properties, from both gas phases and organic solvents.

Implementation Method 1

the complexed metal salt... for chemically binding or adsorbing pollutants and/or odor-forming substances

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

the complexed metal salt... for chemically binding or adsorbing pollutants and/or odor-forming substances

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

wherein the complexing agent with an acid function, in particular the deprotonated acid function as anion, forms a coordinate and/or ionic bond directly with the metal atom

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 4

The ligands have a hydrophobic carbon skeleton with hydrophilic groups... the complexed metal salt formed with the complexing agent is... surface-active

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP2222685B1Surface-active metal complexes on carrier materials for adsorbing noxious substances and method for producing the supported materials
Publication Date: 2014.07.02 CAM D TECH
  • EP2222685B1 patent drawingFigure 1
  • EP2222685B1 patent drawingFigure 2
  • EP2222685B1 patent drawingFigure 3

AI summary

The invention relates to supported structures which are especially useful for chemically binding and/or adsorbing noxious substances and/or odor-producing substances especially having electron donor properties and which comprise a complexed metal salt (metal complex) on a carrier material, the complexed metal salt having at least one ligand and at least one complexing agent, the ligands comprising a hydrophobic carbon skeleton with hydrophilic groups. The complexed metal salt formed with the complexing agent is water-soluble and surface-active. Preferred complexing agents are water-soluble acids or salts of at least bifunctional acids, or ether carboxylic acids.