Surface-Treated Shower Plate for Plasma CVD Corrosion Control

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Solution Overview

Problem

Conventional plasma CVD apparatuses experience changes in film characteristics, such as increased film thickness and reduced elastic modulus, due to corrosion and thermal issues at metal contact surfaces between the shower plate and body, affecting the reliability of high-integration devices.

Innovation Solution

A plasma CVD apparatus with a showerhead featuring a surface-treated peripheral surface to eliminate metal-to-metal contact, providing corrosion resistance and stabilizing film characteristics by controlling the effects of fluorinated radicals and thermal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal-to-metal contact surfaces are used between shower plate and body, then electrical conductivity and RF wave propagation are maintained, but corrosion occurs and film characteristics change

Engineering Contradiction:
Improvefilm characteristics stabilityVSAvoidcorrosion at contact surfaces
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a non-metallic material (such as PTFE or other insulating materials) as an intermediary layer between the metal shower plate and body. This intermediary prevents direct metal-to-metal contact, thereby eliminating corrosion while maintaining electrical conductivity and RF wave propagation through proper material selection and design.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs composite material structures where non-metallic components are integrated with metallic parts. The contact surfaces utilize composite construction that combines the benefits of metal (structural integrity) with non-metal materials (corrosion resistance), creating a hybrid interface that resolves the contradiction between conductivity and corrosion resistance.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional showerhead structure is used, then maintenance is simple and costs are reduced, but film thickness increases and elastic modulus decreases during consecutive deposition

Engineering Contradiction:
Improveshowerhead maintenance simplicityVSAvoidfilm thickness control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent divides the showerhead into separable components (shower plate, body, and intermediary layers) that can be independently maintained or replaced. This segmentation allows for easier maintenance while preventing the degradation issues that affect film thickness control in conventional integrated structures.

Inventive Principle:
Principle #1Segmentation

3Productivity

If metal contact surfaces are exposed to fluorinated radicals, then cleaning process is effective, but contact surfaces become corroded and rough

Engineering Contradiction:
Improvecleaning process efficiencyVSAvoidcontact surface integrity
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The non-metallic intermediary material serves as a protective mediator that shields the metal contact surfaces from direct exposure to corrosive fluorinated radicals during cleaning processes. This allows effective cleaning to occur while the intermediary absorbs or resists the corrosive effects, preserving contact surface integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The surface-treated peripheral surfaces stabilize film thickness and elastic modulus, preventing changes during consecutive deposition processes and ensuring reliable film formation without interfering with electric current or radio-frequency propagation.

Implementation Method 1

at least one of the peripheral surface of the body or the peripheral surface of the shower plate is surface-treated

Methodology Applied
Scientific EffectAnodizing: Anodising

Implementation Method 2

The showerhead 9 and the gas inlet port 5 are insulated from the reaction chamber 6, are connected with radio-frequency sources 7, 8 and form the other side of the electrodes

Methodology Applied
Scientific EffectPlasma discharge: Plasma

Implementation Method 3

The susceptor 3 is supported by a heater 2 which heats the substrate 4 to a given temperature (150-450° C.)

Methodology Applied
Scientific EffectResistive heating: Joule Heating

Data Source

PatentUS7641761B2Apparatus and method for forming thin film using surface-treated shower plate
Publication Date: 2010.01.05 ASM JAPAN
  • US7641761B2 patent drawing
  • US7641761B2 patent drawing
  • US7641761B2 patent drawing

AI summary

A plasma CVD apparatus includes a showerhead comprised of a body having a hollow structure. The shower plate is detachably integrated with the body at a peripheral surface of the body and a peripheral surface of the shower plate, and at least one of the peripheral surface of the body or the peripheral surface of the shower plate is surface-treated.