Nonionic Surfactant Coating for Aqueous Drop Retraction

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Solution Overview

Problem

Hydrophobic surfaces pose challenges for the efficient deposition of aqueous drops, leading to retraction and loss of pesticides, and medical devices with hydrophobic coatings require improved hydrophilicity for easier insertion and reduced water retention issues.

Innovation Solution

A method using a nonionic surfactant mixture with a specific weight ratio of water to surfactant, applied to hydrophobic surfaces to prevent drop retraction, and a hydrophilic coating composition for medical devices that enhances lubricity and adherence without curing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If aqueous dispersion is applied to hydrophobic surface, then deposition efficiency is improved, but drop retraction occurs causing loss of substance

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidpesticide loss
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent introduces a nonionic surfactant mixture as an intermediary substance between the aqueous dispersion and the hydrophobic surface. The surfactant molecules have hydrophilic heads that interact with water and hydrophobic tails that interact with the hydrophobic surface, mediating the interaction and preventing drop retraction while maintaining deposition efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the surface tension parameter of the aqueous dispersion by adding surfactants. This parameter change allows the dispersion to spread and adhere to hydrophobic surfaces without retracting, thereby preventing substance loss while maintaining efficient deposition.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If hydrophobic coating is used on medical device, then device functionality is improved, but water retention and lubricity are worsened

Engineering Contradiction:
Improvedevice functionalityVSAvoidinsertion ease
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies local quality by treating only the surface layer of the medical device with hydrophilic coating while maintaining the bulk hydrophobic properties. This allows the surface to be hydrophilic (improving lubricity and ease of insertion) while the bulk material retains its hydrophobic functionality.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite structure with a hydrophobic bulk material and a hydrophilic surface coating. This composite approach allows the device to exhibit both hydrophobic functionality in its core and hydrophilic surface properties for improved insertion and reduced water retention issues.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If surfactant concentration is increased to prevent retraction, then deposition efficiency is improved, but solution viscosity and cost increase

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidshear viscosity
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent optimizes the surfactant concentration parameter to achieve the minimum effective amount needed to prevent drop retraction. By carefully controlling this parameter, the patent achieves high deposition efficiency while maintaining low solution viscosity and minimizing costs.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses synergistic interactions between different surfactant molecules to achieve enhanced performance at lower concentrations. The combined effect of multiple surfactants provides superior deposition efficiency compared to individual surfactants at equivalent total concentrations, reducing the need for high surfactant amounts.

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively pins aqueous drops on hydrophobic surfaces, reducing retraction by over 95% and enhances the hydrophilicity of medical devices, improving lubricity and water retention while eliminating the need for curing processes.

Implementation Method 1

Aqueous drops of nonionic surfactant combinations prevent retraction of drops after impinging on hydrophobic substrates

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

The efficacy of spreading of aqueous dispersions on hydrophobic substrates is low due to the water drops bouncing off or splashing

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

a hydrophilic coating composition for medical devices that enhances lubricity and adherence

Methodology Applied
Scientific EffectHydrophilicity: Hydrophile

Implementation Method 4

enhances the hydrophilicity of medical devices, improving lubricity

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentUS11925730B2Method for preventing rectraction of aqueous drops and a medical device coated with hydrophilic coating
Publication Date: 2024.03.12 COUNCIL OF SCI & IND RES
  • US11925730B2 patent drawing
  • US11925730B2 patent drawing
  • US11925730B2 patent drawing

AI summary

The present invention discloses a method for preventing retraction of aqueous drops on a hydrophobic surface. The present invention also discloses a medical device coated with a hydrophilic coating comprising a substrate and a coating composition.