Surfactant Mixture for Dishwasher Drying Performance

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Solution Overview

Problem

Modern dishwashing detergents, especially multifunctional agents, face challenges in improving drying performance on hard surfaces like glass and metal, leading to residual water droplets and unaesthetic spots, while also needing to be environmentally friendly and not adversely affect rinsing performance.

Innovation Solution

A combination of specific surface-active substances, including hydroxy mixed ethers and other surfactants, are used in dishwashing detergents to enhance drying performance and maintain rinsing efficacy, with preferred compounds following specific molecular formulas to ensure structural differences and optimal ratios for improved cleaning agents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If multifunctional cleaning agents are used to combine cleaning, rinsing, and water softening functions, then convenience and cost-effectiveness are improved, but drying performance deteriorates leading to water droplets and spots on surfaces

Engineering Contradiction:
ImprovemultifunctionalityVSAvoiddrying performance
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent combines multiple surfactant types (anionic, cationic, nonionic) with different functional properties into a single composition that delivers cleaning, rinsing, softening, and drying functions simultaneously, resolving the contradiction between multifunctionality and drying performance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses composite surfactant systems where different surfactant classes work synergistically - the anionic surfactant provides cleaning, the cationic surfactant aids rinsing and softening, and the nonionic surfactant enhances drying performance, achieving multiple functions without compromise

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If classic rinse aids with silicone or fluorinated compounds are used to improve drying performance, then drying performance is improved, but environmental harm increases due to poor biodegradability

Engineering Contradiction:
Improvedrying performanceVSAvoidenvironmental harm
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent employs biodegradable surfactants that break down rapidly in the environment, replacing persistent silicone and fluorinated compounds with environmentally benign alternatives that perform their drying function and then degrade harmlessly

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention converts the limitation of biodegradable surfactants (traditionally poorer drying performance) into an advantage by carefully selecting and combining specific biodegradable surfactant types that achieve superior drying while maintaining environmental compatibility, turning what was seen as a compromise into a benefit

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If rinse aids are added to improve water drainage and reduce deposits, then rinsing performance is improved, but the complexity of the detergent formulation increases

Engineering Contradiction:
Improverinsing performanceVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent designs surfactant compositions where each surfactant type performs multiple functions - the same anionic, cationic, and nonionic surfactants that provide cleaning also contribute to rinsing and drying, eliminating the need for separate rinse aid formulations and reducing overall complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of selected surface-active substances significantly reduces water droplets on surfaces post-washing, particularly on plastic, enhancing drying performance without compromising rinsing efficiency and ensuring ecological harmlessness.

Implementation Method 1

The task of these agents is there is to influence the interfacial tension of the water in such a way that it can run off the dishes in a film that is as thin as possible

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

The task of these agents is there is to influence the interfacial tension of the water in such a way that it can run off the dishes in a film that is as thin as possible

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentEP2240562B1Use of surface-active substances in cleaning agents
Publication Date: 2011.09.07 COGNIS IP MANAGEMENT GMBH
  • EP2240562B1 patent drawing
  • EP2240562B1 patent drawing
  • EP2240562B1 patent drawing

AI summary

The invention relates to selected surface-active substances of groups a) and b), the surface-active compound a) being selected from compounds of general formula (Ia), wherein M represents a group CH2-CH2 or CHR-CH2, R, R' or R'' independently represent saturated, unsaturated, linear or branched alkyl groups or alkenyl groups with 6 to 22 C atoms, and the indices n and m independently can have values between 1 and 40, and/or compounds of general formula (Ib), wherein R''' and R'''' independently represent saturated, unsaturated, linear or branched alkyl groups or alkenyl groups with 4 to 22 C atoms, and the indices n and m independently can have values between 1 and 40 and X' and X'' independently represent H or saturated, unsaturated, linear or branched alkyl groups or alkenyl groups with 1 to 18 C atoms. The surface active substances of the invention, either on their own or combined with other nonionic surfactants, lead to dishwashing agents with an improved drying performance, especially in multifunctional agents for automatic dishwashers.