Surfactant Dosing Sequence for Gelation Prevention

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Solution Overview

Problem

The incorporation of high concentrations of Sodium Lauryl Ether Sulfate (SLES) into detergent compositions is challenging due to its high viscosity, leading to gelation or clumping issues, which complicates manufacturing and reduces cleaning performance and aesthetics, especially in betaine-free systems using amine oxides.

Innovation Solution

Changing the dosing sequence to first add a solvent, followed by SLES, then amine oxide, and optionally additives, prevents surfactant gelling and allows for simpler mixing techniques, enabling efficient incorporation of SLES into detergent compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentrations of SLES are incorporated into detergent compositions, then cleaning performance is improved, but gelation or clumping occurs leading to aesthetic limitations

Engineering Contradiction:
Improvecleaning performanceVSAvoidgelation or clumping
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by adding SLES to the solvent before adding amine oxide. This specific dosing sequence prevents gelation and clumping by establishing the surfactant solution in a controlled manner before introducing the amine oxide component, thereby maintaining cleaning performance while avoiding aesthetic limitations

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the dosing sequence parameter from the conventional order (solvent, then amine oxide, then SLES) to a modified order (solvent, then SLES, then amine oxide). This parameter change in the addition sequence resolves the contradiction by preventing gelation while maintaining high SLES concentrations for effective cleaning performance

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high concentrations of SLES are incorporated into detergent compositions, then cleaning performance is improved, but special mixing equipment is required increasing investment and operating costs

Engineering Contradiction:
Improvecleaning performanceVSAvoidmixing equipment
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

By performing the preliminary action of adding SLES to solvent first and allowing it to dissolve completely before adding amine oxide, the patent enables the use of simple mixing equipment. The controlled dosing sequence prevents gelation that would otherwise require complex mixing devices, thereby reducing investment and operating costs while maintaining cleaning performance

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the dosing sequence parameter to enable simple mixing techniques. This parameter modification allows standard mixing equipment to handle high SLES concentrations effectively, eliminating the need for specialized expensive equipment while achieving the desired cleaning performance

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional dosing sequence is used (solvent, then amine oxide, then SLES), then manufacturing is simplified, but surfactants gelate reducing cleaning performance and aesthetics

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcleaning performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies the inversion principle by reversing the conventional dosing sequence. Instead of adding amine oxide before SLES, the patent adds SLES before amine oxide. This inverted sequence prevents gelation and maintains cleaning performance while preserving manufacturing simplicity

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent changes the dosing sequence parameter from the conventional order to a modified order that prevents gelation. This parameter change maintains the simplicity of the manufacturing process while ensuring high cleaning performance by preventing surfactant gelation

Inventive Principle:
Principle #35Parameter changes

4Device complexity

If simple stirring geometries are used, then equipment complexity is reduced, but incorporation of large amounts of SLES without gelation or clumping is not possible

Engineering Contradiction:
Improvestirring geometryVSAvoidsurfactant incorporation
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent applies preliminary action by adding SLES to solvent first and allowing complete dissolution before introducing amine oxide. This sequence enables simple stirring geometries to effectively incorporate large amounts of SLES without gelation or clumping, as the surfactant is introduced in a controlled manner that prevents aggregation

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the dosing sequence parameter to enable effective mixing with simple stirring geometries. This parameter modification allows large amounts of SLES to be incorporated homogeneously without gelation or clumping, maintaining device simplicity while ensuring reliable surfactant incorporation

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3819360A1Improved solubility of surfactant systems through adaptation of the addition of raw materials
Publication Date: 2021.05.12 HENKEL KGAA
  • EP3819360A1 patent drawing
  • EP3819360A1 patent drawing
  • EP3819360A1 patent drawing

AI summary

The invention relates to a process for producing surfactant-containing compositions for use as detergents and cleaning agents, comprising or consisting of the following steps: (a) placing at least one solvent in a container; then (b) adding at least one fatty alcohol ether sulfate; then (c) adding at least one amine oxide; and then optionally (d) adding at least one additive; wherein the components are optionally mixed after step (b) and/or (c) and/or (d). The invention further relates to a detergent and cleaning agent obtainable by the process according to the invention.