Surfactant Compositions for Gelled Layer Prevention in Oil Wells

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Solution Overview

Problem

The formation of gelled layers in oil and gas wells poses challenges for hydrocarbon recovery, as existing methods are inadequate in preventing, breaking down, and removing these layers, leading to reduced productivity and efficiency in well operations.

Innovation Solution

The use of surfactant-based compositions, including concentrates and emulsions or microemulsions containing sulfonates, polyimines, EO/PO block copolymers, and ethoxylated quaternary ammonium compounds, is introduced to prevent the formation and facilitate the breakdown and removal of gelled layers in oil and gas wells.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If gel-breaking agents are used to overcome gelled layers, then some breakdown effect is achieved, but the effectiveness is insufficient and gelled layers still hinder productivity

Engineering Contradiction:
Improvewell productivityVSAvoideffectiveness of gel breakdown
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the treatment fluid by incorporating specific surfactants (sulfonates and polyimines) that alter the interfacial properties between oil and water phases. This parameter change enables effective breakdown of gelled layers that conventional gel-breaking agents cannot handle, directly addressing the insufficiency of existing methods while improving well productivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite surfactant systems combining sulfonates and polyimines in specific formulations. This composite approach creates synergistic effects that provide reliable gel breakdown capability, overcoming the limitations of single-agent systems and ensuring consistent effectiveness in removing gelled layers to restore productivity

Inventive Principle:
Principle #40Composite materials

2Productivity

If fluids are injected to perform multiple tasks simultaneously, then operational efficiency is improved, but achieving optimal characteristics for all tasks becomes difficult

Engineering Contradiction:
Improveoperational efficiencyVSAvoidfluid characteristic optimization
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The surfactant-based composition is designed to perform multiple functions simultaneously: preventing gelled layer formation, breaking down existing gelled layers, and improving hydrocarbon recovery. This multi-functional fluid addresses the challenge of achieving optimal characteristics for multiple tasks while maintaining operational efficiency in well operations

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of operation

If conventional gel-breaking agents are used, then some gelled layer removal is achieved, but the methods are inadequate and require improved techniques

Engineering Contradiction:
Improvegelled layer removal capabilityVSAvoidadequacy of removal method
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The surfactant composition acts as an intermediary substance that facilitates the breakdown of gelled layers by reducing interfacial tension between oil and water phases. This intermediary mechanism provides reliable and adequate removal capability that conventional direct-breaking agents cannot achieve, making the operation both easier and more effective

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These surfactant-based compositions effectively prevent the formation and enhance the breakdown of gelled layers, improving hydrocarbon recovery by ensuring smoother fluid flow and reducing the presence of gelled layers that hinder well productivity.

Implementation Method 1

injecting a concentrate comprising one or more surfactants into the wellbore, wherein the surfactant comprises a sulfonate and/or a polyimine

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS10294757B2Methods and compositions related to gelled layers in oil and/or gas wells
Publication Date: 2019.05.21 FLOTEK CHEMISTRY LLC
  • US10294757B2 patent drawing

AI summary

Methods and compositions for the prevention of the formation, breakdown, and/or removal of gelled layers in an oil and/or gas well are provided. In some embodiments, the compositions and methods comprise a concentrate, as described in more detail herein, where the concentrate comprises two or more surfactants. In certain embodiments, the compositions and methods comprise an emulsion or a microemulsion. The emulsion or microemulsion may include a surfactant, optionally a solvent, and optionally a freezing point depression agent or other components.