Nonionic Surfactant and Cationic Polymer Complex for Tissue Softening

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional softening compounds for tissue papers, particularly quaternary ammonium surfactants, pose environmental and health concerns due to toxicity and irritation, necessitating the development of alternative compositions that can effectively soften paper products while being non-toxic and environmentally friendly.

Innovation Solution

A composition comprising nonionic surfactants and cationic polymers, specifically poly(DADMAC) of varying molecular weights, is used to create a synergistic debonding effect that reduces fiber bonding interactions, enhancing softness without the need for anionic components, thus avoiding harmful labeling and environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If quaternary ammonium surfactants are used as softening compounds, then softness is improved, but environmental safety and health profile deteriorate due to toxicity and irritation

Engineering Contradiction:
ImprovesoftnessVSAvoidtoxicity and environmental harm
Core Design Contradiction:
ShapeVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing quaternary ammonium surfactants with a combination of nonionic surfactants and cationic polymers. This substitution maintains the softening function while eliminating toxic effects, achieving both softness improvement and environmental safety

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite system combining nonionic surfactants and cationic polymers to achieve the softening effect. This composite approach replaces the single-component quaternary ammonium surfactant system, providing both functional equivalence and improved safety profile

Inventive Principle:
Principle #40Composite materials

2Shape

If softening compounds are added to cellulosic suspension, then surface softness is improved, but fiber bonding is reduced leading to weaker paper structure

Engineering Contradiction:
Improvesurface softnessVSAvoidfiber bonding strength
Core Design Contradiction:
ShapeVSStrength

Solution Approach 1:

The patent applies softening locally at the fiber surface level rather than throughout the entire fiber structure. The nonionic surfactant and cationic polymer combination targets the fiber surface to reduce harshness while preserving the bulk fiber bonding integrity, achieving surface softness without compromising overall strength

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves significant tensile strength reduction in paper products, comparable to industry standards, while being free from toxic and hazardous labeling, ensuring improved environmental and health profiles.

Implementation Method 1

A synergistic debonding effect is achieved by a nonionic surfactant and a cationic polymer

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 2

The softener comprises a nonionic surfactant and a cationic polymer

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentEP2734673B1Debonder and softener compositions
Publication Date: 2017.05.10 NALCO CO

AI summary

Methods and compositions for softening paper. An inventive composition and method of its use softens paper products (like tissue paper) by de-bonding its cellulose fibers and by improving the smoothness of the resulting paper. The invention forms a surfactant-polymer complex that attaches de-bonding non-ionic surfactants to cellulose fibers that would otherwise not be retained by the cellulose fibers. This complex prevents the fibers from bonding with each other and makes the paper product smoother. Best of all, the composition is environmentally superior and is a non-toxic.