Susceptor CF Coating Seals Anodized Layer Cracks

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Solution Overview

Problem

Exposure of base metal due to cracks in the anodized layer of a susceptor during substrate processing leads to the generation of aluminum-containing gases, causing contamination and foreign matter formation on the substrate during plasma treatment.

Innovation Solution

A susceptor coating method involving a fluorocarbon (CF) polymer coating applied within the cracks of the anodized layer to prevent exposure of the base metal, ensuring a stable and contamination-free substrate processing environment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If an anodized layer is formed on the base metal to prevent contamination, then the substrate processing quality is improved, but cracks occur in the anodized layer causing base metal exposure

Engineering Contradiction:
Improvesubstrate processing qualityVSAvoidanodized layer integrity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies a CF coating specifically to the cracked regions of the anodized layer through plasma CVD processing. This localized treatment seals the cracks and prevents base metal exposure at critical areas while maintaining the overall structure of the anodized layer. The coating is selectively formed where needed to address the reliability issue without compromising the manufacturing precision achieved by the anodized layer.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite structure by combining the anodized layer with a CF (fluorocarbon) coating. The anodized layer provides the primary protective barrier, while the CF coating fills and seals the cracks in the anodized layer. This composite approach integrates two different materials with complementary properties to simultaneously achieve both manufacturing precision and reliability.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If the base metal is exposed due to cracks, then the anodized layer structure is simpler, but aluminum-containing gases are generated causing contamination

Engineering Contradiction:
Improvesusceptor structureVSAvoidaluminum contamination
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful aluminum-containing gases generated from exposed base metal by introducing cleaning gas (such as CF4 or C2F6) to react with and eliminate the aluminum contamination. The plasma processing removes aluminum particles and prevents their deposition on substrates, effectively extracting the harmful elements from the system.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the harmful aluminum-containing gases into beneficial byproducts by using fluorocarbon cleaning gas to react with the exposed aluminum. The reaction transforms aluminum particles into volatile aluminum fluoride compounds that can be easily removed, turning the contamination problem into a controlled chemical process that eliminates the harm.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-affected harmful factors

If cleaning gas is used to remove aluminum contamination, then the chamber is cleaner, but gas containing aluminum is generated from exposed base metal

Engineering Contradiction:
Improvechamber contaminationVSAvoidaluminum gas generation
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by first forming the CF coating to seal the cracks in the anodized layer before substrate processing begins. This preventive measure eliminates the source of aluminum gas generation at the outset, so that subsequent cleaning gas exposure does not produce aluminum-containing contaminants. The cracks are sealed in advance to prevent the harmful reaction chain.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies preliminary anti-action by introducing the CF coating as a protective barrier before any contamination can occur. This coating prevents the cleaning gas from contacting the exposed base metal, thereby preemptively blocking the generation of aluminum-containing gases. The anti-action is taken in advance to neutralize the potential harmful interaction between cleaning gas and exposed aluminum.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The CF coating effectively suppresses the exposure of the base metal, enhancing the quality of substrate processing by preventing aluminum contamination and maintaining a clean chamber environment.

Implementation Method 1

a CF coating of polymer provided in the cracks

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Implementation Method 2

The anodized layer is a layer formed by anodizing the base metal

Methodology Applied
Scientific EffectAnodizing: Anodising

Implementation Method 3

the base metal is exposed to cleaning gas containing F to generate AlF

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

the thus-generated AlF gasifies

Methodology Applied
Scientific EffectGasification: Evaporation

Data Source

PatentUS11359302B2Susceptor having CF coating
Publication Date: 2022.06.14 ASM IP HLDG BV
  • US11359302B2 patent drawing
  • US11359302B2 patent drawing
  • US11359302B2 patent drawing

AI summary

Examples of a susceptor for supporting a substrate includes a base metal formed of aluminum or a material containing aluminum, an anodized layer covering a surface of the base metal and having cracks therein, and a CF coating of polymer provided in the cracks such that the exposure of the base metal is avoided.