Sweep-Based Membrane Separation for Flue Gas Carbon Dioxide Capture

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Solution Overview

Problem

Current methods for treating flue gases contaminated with carbon dioxide from combustion processes are technically and economically inefficient, requiring more effective techniques to reduce carbon dioxide emissions and minimize environmental impact.

Innovation Solution

A membrane-based gas separation process combining a sweep-based membrane separation with an absorption step, where a portion of the flue gas is treated using membranes selectively permeable to carbon dioxide, and the carbon dioxide-enriched permeate stream is recycled back to the combustion process, enhancing carbon dioxide concentration and reducing emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional flue gas treatment methods are used, then carbon dioxide removal is achieved, but the process is technically and economically inefficient

Engineering Contradiction:
Improvecarbon dioxide removal efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The flue gas stream is divided into two separate streams: one treated by absorption and another by membrane separation. This segmentation allows each process to handle a portion of the carbon dioxide removal task, improving overall efficiency while maintaining manageable process complexity through modular design

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the concentration parameter of carbon dioxide in the flue gas by using membrane separation to enrich one stream before absorption treatment. This parameter change enhances the effectiveness of the absorption process and reduces the volume of gas requiring treatment, thereby improving productivity without proportionally increasing device complexity

Inventive Principle:
Principle #35Parameter changes

2Productivity

If flue gas is transported for carbon dioxide capture, then capture is achieved, but transportation cost and complexity increase

Engineering Contradiction:
Improvecarbon dioxide capture rateVSAvoidgas volume for transport
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The membrane separation unit extracts and concentrates carbon dioxide from the flue gas stream, creating a smaller, more concentrated stream that requires less transportation volume. This extraction step reduces the quantity of gas that needs to be transported while maintaining high capture productivity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

By changing the concentration parameter through membrane enrichment, the invention reduces the total volume of gas requiring transportation. The enriched stream contains higher carbon dioxide concentration, allowing the same capture productivity to be achieved with reduced transport quantity and associated costs

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If flue gas is discharged to environment, then process simplicity is maintained, but environmental damage occurs

Engineering Contradiction:
Improveenvironmental impactVSAvoidprocess complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The flue gas stream is segmented into two treatment paths: absorption for bulk carbon dioxide removal and membrane separation for polishing and enrichment. This segmentation enables effective environmental protection by treating different portions of the gas stream with appropriately sized units, managing process complexity through modular architecture

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The membrane separation process changes the carbon dioxide concentration parameter, creating an enriched stream that can be efficiently captured and a depleted stream that meets emission standards. This parameter transformation reduces environmental impact while maintaining reasonable process complexity through targeted treatment

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases carbon dioxide concentration in the exhaust stream, simplifies and reduces the cost of transporting the gas for capture, and minimizes carbon dioxide in vent streams, thereby reducing environmental impact.

Implementation Method 1

a membrane having a feed side and a permeate side, and being selectively permeable to carbon dioxide over nitrogen and to carbon dioxide over oxygen

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

membranes selectively permeable to carbon dioxide

Methodology Applied
Scientific EffectSelective permeability: Semipermeable Membrane

Implementation Method 3

passing a sweep gas across the permeate side of the membranes, thereby lowering the partial pressure of a desired permeant on that side to a level below its partial pressure on the feed side

Methodology Applied
Scientific EffectPartial pressure gradient: Pressure Gradient

Implementation Method 4

an absorption-based carbon dioxide capture step

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentEP2616162B1Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps
Publication Date: 2017.03.15 MEMBRANE TECHNOLOGY & RESEARCH INC
  • EP2616162B1 patent drawingFigure 1
  • EP2616162B1 patent drawingFigure 2
  • EP2616162B1 patent drawingFigure 3

AI summary

A gas separation process for treating flue gases (117) from combustion processes (112), and combustion processes including such gas separation. The invention involves routing a first portion (106) of the flue gas stream to be treated to an absorption -based carbon dioxide capture step (113), while simultaneously flowing a second portion (103) of the flue gas across the feed side of a membrane (118), flowing a sweep gas stream (101), usually air, across the permeate side, then passing the permeate/sweep gas to the combustor (112).