Sweetener Composition With Calcium Salts for Browning Control

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Solution Overview

Problem

Reducing saccharides, such as allulose and polydextrose, exhibit excessive browning and acrylamide formation when heated in the presence of amine-containing food ingredients, limiting their use in cooked or baked food products.

Innovation Solution

Incorporating a divalent metal ion salt, particularly calcium salts, into a sweetener composition with reducing saccharides to reduce browning and acrylamide formation during heating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If reducing saccharides are used as sweeteners, then calorie content is reduced, but excessive browning and acrylamide formation occur during heating

Engineering Contradiction:
Improvecalorie contentVSAvoidbrowning and acrylamide formation
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

A divalent metal ion salt acts as an intermediary substance between the reducing saccharide and the harmful browning/acrylamide formation process. The metal ion salt interferes with the chemical reactions that cause excessive browning and acrylamide generation, allowing the reducing saccharide to maintain its low-calorie advantage without producing harmful byproducts during heating.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If reducing saccharides are heated in the presence of amine-containing food ingredients, then Maillard reaction occurs, but excessive browning and acrylamide formation result

Engineering Contradiction:
ImproveMaillard reactionVSAvoidexcessive browning and acrylamide formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The divalent metal ion salt serves as a mediator that modulates the Maillard reaction between reducing saccharides and amine-containing food ingredients. It allows the reaction to proceed sufficiently for flavor development while preventing the excessive browning and acrylamide formation that would otherwise occur.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The divalent metal ion salt changes the chemical parameters of the heating environment, specifically affecting the reaction kinetics and thermodynamics of the Maillard reaction. This modification of reaction parameters enables controlled browning appropriate for food products while preventing excessive darkening and harmful acrylamide generation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of divalent metal ion salts, like calcium chloride, effectively minimizes excessive browning and acrylamide formation in food products, resulting in lighter-colored and safer baked goods.

Implementation Method 1

the use of a divalent metal ion salt for the reduction of browning of a reducing saccharide and/or the formation of acrylamide during heating in the presence of an amine-containing food ingredient

Methodology Applied
Scientific EffectMetal ion interaction:

Implementation Method 2

the use of a divalent metal ion salt for the reduction of browning of a reducing saccharide and/or the formation of acrylamide during heating in the presence of an amine-containing food ingredient

Methodology Applied
Scientific EffectChemical reaction inhibition:

Data Source

PatentUS20250338860A1Sweetener composition, method for reducing browning, and food product
Publication Date: 2025.11.06 TATE & LYLE SOLUTIONS USA LLC
  • US20250338860A1 patent drawing
  • US20250338860A1 patent drawing
  • US20250338860A1 patent drawing

AI summary

A divalent metal ion salt, such as a calcium salt, for the reduction of browning of a reducing saccharide and/or the formation of acrylamide during heating in the presence of an amine-containing food ingredient: a sweetener composition comprising a divalent metal ion salt and a reducing saccharide: use of a divalent metal ion salt for the reduction of browning and acrylamide formation in a food product comprising a reducing saccharide during heating in the presence of an amine-containing additional food ingredient: a method for reducing browning and acrylamide formation in a food product, wherein the method comprises: a) combining a reducing saccharide with a divalent metal salt and at least one amine-containing additional food ingredient to provide an unheated food product; and b) optionally heating the unheated food product to provide a heated food product; and a food product comprising: a reducing saccharide, a divalent metal ion salt, and an amine-containing additional food ingredient.