Elastomer with Swellable Metal for Wellbore Sealing

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Solution Overview

Problem

Conventional swellable packers used in wellbore operations, which rely on osmosis-driven expansion, face challenges in maintaining sealing pressure in dry gas wells due to water loss, leading to reduced volume and sealing efficiency.

Innovation Solution

A sealing apparatus comprising an elastomer embedded with a swellable metal that expands through hydrolysis in response to aqueous or oil-based fluids, providing a hybrid swelling mechanism to maintain sealing pressure across varying downhole conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional swellable packer uses osmosis-driven expansion with superabsorbent polymer or salt, then the elastomer can expand in volume to provide sealing pressure, but the sealing pressure is lost in dry gas wells when water leaves the elastomer matrix causing volume decrease

Engineering Contradiction:
Improvesealing pressure maintenanceVSAvoidelastomer volume stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the swelling mechanism from osmosis-driven (dependent on water concentration gradients) to hydrolysis-driven (dependent on water reaction with metal). This parameter change in the chemical mechanism allows the elastomer to swell when exposed to aqueous fluids in wet gas wells while avoiding the volume loss problem in dry gas wells where water would otherwise leave the matrix.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining elastomer with embedded swellable metal particles. This composite structure enables the elastomer to gain swelling capability through metal hydrolysis rather than relying solely on osmosis, providing stable sealing pressure across varying downhole conditions including both wet and dry gas environments.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the elastomer relies on osmosis for swelling, then water can drive the swelling process, but changes in downhole conditions can reverse the swelling process

Engineering Contradiction:
Improveswelling response to fluid conditionsVSAvoidsealing pressure consistency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the chemical mechanism from reversible osmosis to irreversible hydrolysis. The hydrolysis reaction between water and metal particles produces metal hydroxide and hydrogen gas, creating a permanent volume increase that does not reverse when downhole conditions change, thereby maintaining reliable sealing pressure consistency.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If the elastomer uses superabsorbent polymer or salt for swelling, then the material can control swell volume through concentration, but the swelling is dependent on molar concentration of dissolved chemical species

Engineering Contradiction:
Improveswell volume controlVSAvoidswelling mechanism dependency
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent changes the swelling dependency from molar concentration of dissolved species (osmosis) to mass-based metal particle concentration (hydrolysis). This allows the elastomer to control swell volume through the concentration of metal particles embedded in the matrix, providing versatility across different fluid compositions and downhole conditions without being limited by dissolved chemical species concentration.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The apparatus ensures consistent zonal isolation and flow restriction by increasing volume through metal hydroxide or oxide formation, maintaining sealing pressure regardless of fluid composition and downhole conditions.

Implementation Method 1

The swellable metal, when exposed to a downhole fluid such as an aqueous fluid, may expand in size by transitioning from a first configuration having a first volume to an expanded configuration having a second volume. During this expansion, water may react with the swellable metal to cause the volume of the swellable metal to increase

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

Osmosis may drive water into the elastomer causing the superabsorbent polymer or salt to hydrate and increase in volume

Methodology Applied
Scientific EffectOsmosis: Osmosis

Implementation Method 3

water may react with the swellable metal to cause the volume of the swellable metal to increase, thereby increasing the total volume of the elastomer with the embedded swellable metal

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS11136850B2Elastomer with an expandable metal
Publication Date: 2021.10.05 HALLIBURTON ENERGY SERVICES INC
  • US11136850B2 patent drawing
  • US11136850B2 patent drawing
  • US11136850B2 patent drawing

AI summary

A method may comprise: inserting an apparatus into a wellbore, wherein the apparatus comprises: a seal element comprising: an elastomer; and a swellable metal embedded in the elastomer; exposing the seal element to a fluid; transitioning the seal element from an initial state with an initial volume to an expanded state with an expanded volume to form a seal in the wellbore.