Synergistic Biocide Composition for Industrial Water Microbial Control

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Solution Overview

Problem

Industrial water systems face significant challenges with microbial growth and slime deposits, leading to costly control programs and process inefficiencies, with no single compound effectively addressing these issues.

Innovation Solution

A synergistic composition of hydantoin-stabilized hypochlorite and peracetic acid is used to inhibit microbial growth and slime deposits, providing enhanced bactericidal activity and reducing the need for high biocide levels, with hydantoin-stabilized hypochlorite generated on-site and peracetic acid applied separately to prevent antagonism.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high levels of biocides are used to control microbial growth, then microbial control efficacy is improved, but corrosion and environmental impact worsen

Engineering Contradiction:
Improvemicrobial control efficacyVSAvoidcorrosion and environmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent combines peracetic acid and hydantoin-stabilized hypochlorite into a synergistic composition where the two biocides work together to achieve enhanced microbial control at lower concentrations. This merging allows the system to maintain high efficacy while reducing the harmful effects associated with using high levels of a single biocide.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses a composite biocidal system comprising peracetic acid and hydantoin-stabilized hypochlorite. This composite approach leverages the complementary properties of both components to achieve superior performance with reduced dosage, thereby minimizing corrosion and environmental impact while maintaining effective microbial control.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If single biocidal compounds are used to control microorganisms, then application simplicity is improved, but control effectiveness worsens

Engineering Contradiction:
Improveapplication simplicityVSAvoidcontrol effectiveness
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent merges peracetic acid and hydantoin-stabilized hypochlorite into a single synergistic composition that can be applied together, maintaining application simplicity while achieving superior control effectiveness compared to using individual biocides alone.

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If peracetic acid and hydantoin-stabilized hypochlorite are mixed, then synergistic bactericidal activity is improved, but composition stability worsens

Engineering Contradiction:
Improvebactericidal activityVSAvoidcomposition stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent segments the biocidal system into two separate compositions: peracetic acid and hydantoin-stabilized hypochlorite. These can be stored and handled separately to maintain stability, then combined at the point of application to achieve synergistic bactericidal activity, thus resolving the contradiction between stability and efficacy.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The hydantoin compound acts as a stabilizing intermediary that allows hypochlorite to be stored in a stable form and then released to provide synergistic activity when combined with peracetic acid. This intermediary approach enables the system to maintain stability during storage while achieving enhanced bactericidal activity during use.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination achieves a higher degree of bactericidal activity than individual components, allowing for reduced biocide usage, effective slime control, and minimal corrosion or environmental impact, addressing the unmet need in industrial water systems.

Implementation Method 1

hydantoin-stabilized halide or halogen-based hydantoin

Methodology Applied
Scientific EffectComplexation: Chemical Bonding

Implementation Method 2

peracetic acid and a composition comprising hydantoin-stabilized halide or halogen-based hydantoin

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3284740B1Synergistic method for inhibiting growth of microorganisms
Publication Date: 2020.10.28 NALCO CO
  • EP3284740B1 patent drawing
  • EP3284740B1 patent drawing
  • EP3284740B1 patent drawing

AI summary

The present invention provides a composition and method for inhibiting the growth of microorganisms in industrial water systems. Methods employing the composition comprising halogen-based hydantoin or hydantoin-stabilized halogen in combination with peracetic acid demonstrate synergistic control of microbial growth, particularly control of slime deposition.