Syntactic Metal Matrix Composite Forming Without Microballoon Crushing

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Solution Overview

Problem

Existing syntactic metal foams face challenges in deformation processing due to the crushing of ceramic microballoons, leading to unpredictable properties and limited use in shaping, with issues of non-uniform porosity and reduced strength at high loading rates and thin walled microballoons.

Innovation Solution

The development of deformation worked syntactic metal foam composites with a metallic matrix and ceramic microballoons, where the microballoons are coated with a metallic layer and processed to maintain uniform porosity and strength, allowing deformation above the average crush strength without fracturing, and achieving high ductility and energy absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If deformation processing is applied to syntactic metal foam, then workability and ductility are improved, but ceramic microballoons are crushed leading to non-uniform porosity and reduced strength

Engineering Contradiction:
ImproveworkabilityVSAvoiduniformity of porosity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies temperature and pressure parameters during deformation processing to control the behavior of ceramic microballoons. By heating to specific temperatures (e.g., 400-600°C for aluminum matrices) and applying controlled pressures, the matrix metal becomes sufficiently ductile to deform while the ceramic microballoons remain intact, resolving the contradiction between workability and porosity uniformity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material design where ceramic microballoons are embedded in a metal matrix with specific properties. The matrix material is selected and processed to have appropriate ductility and strength characteristics that protect the ceramic microballoons during deformation, enabling both workability and structural integrity to coexist

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If high volume fraction of ceramic microballoons is used, then porosity and lightweight properties are improved, but microballoons are more prone to crushing during processing

Engineering Contradiction:
Improvevolume fraction of microballoonsVSAvoidcrush resistance
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent modifies processing parameters including temperature, pressure, and deformation rate to accommodate high volume fractions of ceramic microballoons. By controlling these parameters, the process enables processing of composites with 30-70% microballoon volume fractions while preventing crushing through optimized thermal and mechanical conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary heating and gradual deformation steps before final shaping. This preliminary action softens the matrix metal and prepares the composite structure, allowing high volume fraction microballoons to be positioned and stabilized before subjected to higher deformation loads, preventing crushing

Inventive Principle:
Principle #10Preliminary action

3Weight of stationary object

If thin-walled microballoons are used, then density is reduced and porosity is increased, but microballoons lack sufficient strength to withstand processing loads

Engineering Contradiction:
ImprovedensityVSAvoiduniaxial crush strength
Core Design Contradiction:
Weight of stationary objectVSStrength

Solution Approach 1:

The patent uses temperature parameter changes to compensate for the reduced strength of thin-walled microballoons. By processing at elevated temperatures, the matrix metal becomes more ductile and the microballoons gain thermal strength, allowing thin-walled structures to be processed without crushing while maintaining low density

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The metal matrix acts as an intermediary that protects thin-walled microballoons during processing. The matrix material is selected to provide adequate support and load distribution, preventing direct stress concentration on the thin walls while allowing the microballoons to maintain their lightweight, porous structure

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in syntactic metal foam composites with improved ductility, energy absorption, and workability, enabling their use in applications like armor and lightweight structures without significant reduction in porosity, and achieving densities 40-65% of pore-free matrix metals.

Implementation Method 1

The nickel coating on the fly ash is said to enhance the wetting of the fly ash by the molten matrix metal, thereby reducing the pressure required to force the molten metal through the body of fly ash

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 2

Nakao U.S. Pat. No. 3,781,170, which is hereby incorporated herein by reference as though fully set forth hereat, proposes the production of lightweight metal composite material from a mixture of hollow microspheres in a light metal matrix powder. Heat and pressure are applied to the mixture.

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS11407028B2Syntactic metal matrix materials and methods
Publication Date: 2022.08.09 POWDERMET INC
  • US11407028B2 patent drawing
  • US11407028B2 patent drawing

AI summary

A syntactic metal foam composite that is substantially fully dense except for syntactic porosity is formed from a mixture of ceramic microballoons and matrix forming metal. The ceramic microballoons have a uniaxial crush strength and a much higher omniaxial crush strength. The mixture is continuously constrained while it is consolidated. The constraining force is less than the omniaxial crush strength. The substantially fully dense syntactic metal foam composite is then constrained and deformation worked at a substantially constant volume. The deformation working is typically performed at a yield strength that is adjusted by way of selecting a working temperature at which the yield strength is approximately less than the omniaxial crush strength of the included ceramic microballoons. This deformation causes at least work hardening and grain refinement in the matrix metal.