Fluorinated Coating on Syringe Needle Internal Walls

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Solution Overview

Problem

Applying a uniform, durable, and food-grade fluorinated or ceramic coating to the internal walls of small-diameter tubes, such as syringe needles, is challenging due to their small diameter, requiring improved adhesion and resistance, which existing methods fail to achieve consistently.

Innovation Solution

A method involving mechanical etching of the internal surface using a wire, followed by suction and flow of a coating liquid, desolvation by forced air circulation, and curing, which includes repeating suction and desolvation steps, and using a tungsten diamond wire or chemical attack to enhance coating grip and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional coating methods are used on small-diameter tubes, then the coating application process is simple, but the coating uniformity and adhesion are poor

Engineering Contradiction:
Improvecoating uniformityVSAvoidcoating process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies preliminary mechanical etching of the tube internal surface before coating application. This pre-treatment creates a textured surface that enhances subsequent coating adhesion and uniformity. The etching step prepares the surface in advance to receive the coating more effectively, resolving the contradiction by adding a preparatory action that improves outcomes without requiring complex coating application equipment.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces conventional chemical etching methods with a mechanical etching system using a wire or brush that physically abrasions the internal surface. This mechanical approach provides better control over surface texture and etching depth, achieving more uniform coating preparation while avoiding the variability and safety issues of chemical methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If the tube internal diameter is small, then the tube can be used for syringe needles and sampling, but achieving uniform coating becomes extremely difficult

Engineering Contradiction:
Improvecoating thickness uniformityVSAvoidcoating application ease
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The mechanical etching step is performed as a preliminary action before coating application. By pre-texturing the internal surface with controlled abrasion, the subsequent coating application becomes much easier to control for uniform thickness, even in small-diameter tubes where conventional methods fail.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The mechanical etching creates an intermediary textured surface layer that acts as a mediator between the smooth tube wall and the coating material. This intermediate surface structure facilitates uniform coating distribution and adhesion in the constrained geometry of small-diameter tubes.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If chemical attack is used to prepare the internal surface, then coating adhesion is improved, but food-grade requirements and safety are compromised

Engineering Contradiction:
Improvecoating adhesionVSAvoidchemical residue contamination
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent substitutes chemical etching with mechanical etching using a wire or brush. This replacement eliminates chemical residues that would contaminate food-grade applications while maintaining the surface preparation benefits needed for coating adhesion. The mechanical approach provides controlled surface texture without introducing harmful chemical substances.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent converts the potential harm of aggressive surface preparation into a benefit by using controlled mechanical abrasion. Instead of using harmful chemicals that leave residues, the mechanical etching creates the necessary surface texture through physical means, turning a potentially harmful process into a safe and controllable one.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Manufacturing precision

If multiple suction and desolvation steps are repeated, then coating uniformity and quality improve, but processing time increases

Engineering Contradiction:
Improvecoating qualityVSAvoidcoating process time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The mechanical etching is performed as a preliminary action that sets up the surface for optimal coating reception. This pre-preparation reduces the number of repeated suction and desolvation cycles needed, as the surface is already optimized to receive and hold the coating uniformly, thereby reducing overall process time while maintaining quality.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent implements continuous mechanical etching during the coating application process rather than as a separate discrete step. This continuous action ensures consistent surface preparation throughout the coating deposition, eliminating the need for multiple separate treatment cycles and reducing total processing time while maintaining coating uniformity.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method ensures a uniform, high-quality coating with excellent adhesion and durability, preventing condensation issues and allowing simultaneous processing of multiple tubes, achieving optimal coating performance.

Implementation Method 1

The step of preparing the internal surface is carried out by mechanical etching, the step of preparing the internal surface being carried out using a wire introduced into the internal tube and animated by a movement back and forth against the inner wall of the tube

Methodology Applied
Scientific EffectAbrasion: Abrasion

Implementation Method 2

suction and/or flow in the tube of a liquid containing the coating; emptying of the liquid contained in the tube, at the end of which a deposit of coating on the internal wall of the tube is obtained

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

desolvation of the coating by forced air circulation

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 4

curing of the coating

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentEP3705192B1Method for applying a fluorinated and/or ceramic coating to an internal wall of a low diameter tube, such as a syringe needle
Publication Date: 2021.07.07 SLUPECKI ANNIE
  • EP3705192B1 patent drawingFigure 1

AI summary

The invention relates to a method for applying a colored fluorinated and/or ceramic coating to an internal wall of a small diameter tube such as a syringe needle, comprising the steps of: - aspirating and/or flowing a liquid containing the coating into the tube; - emptying the liquid contained in the tube, at the end of which a coating deposit is obtained on the internal wall of the tube; - desolvation of the coating by forced air circulation; - baking of the coating.