System and method for re-liquefying ammonia boil-off gas of vessel

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Solution Overview

Problem

Conventional methods struggle to effectively reliquefy ammonia boil-off gas for ships, leading to fuel waste and potential pressure instability in storage tanks, which is critical as ammonia is a promising eco-friendly fuel but produces boil-off gas due to its higher boiling point compared to LNG.

Innovation Solution

A system and method involving multistage compression and cooling of ammonia boil-off gas using a compression unit, condenser, and heat exchangers to reliquefy the gas, with temperature regulation through partial diversion of ammonia in a temperature regulation line or side streamline, and pressure control via relief valves, ensuring efficient recovery and stable tank pressure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If ammonia is used as fuel in ships, then greenhouse gas emissions are reduced, but boil-off gas is generated due to ammonia's higher boiling point

Engineering Contradiction:
Improvegreenhouse gas emissionsVSAvoidammonia fuel loss
Core Design Contradiction:
Object-generated harmful factorsVSLoss of substance

Solution Approach 1:

The patent applies phase transition by compressing and cooling the boil-off gas to convert it from gaseous state back to liquid state, enabling it to be returned to the storage tank. The system uses compressors to increase pressure and condensers/heat exchangers to reduce temperature, transforming the ammonia from gas to liquid phase for recovery.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent converts the harmful boil-off gas (which would otherwise be wasted or vented) into a beneficial resource by reliquefying it and returning it to the storage tank. The system transforms what was previously a loss into recoverable fuel, improving overall fuel efficiency.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Stability of the object's composition

If boil-off gas is vented to maintain storage tank pressure, then pressure stability is maintained, but fuel waste occurs

Engineering Contradiction:
Improvestorage tank pressureVSAvoidammonia fuel waste
Core Design Contradiction:
Stability of the object's compositionVSLoss of substance

Solution Approach 1:

The patent implements a feedback mechanism where the reliquefied ammonia is returned to the storage tank, creating a closed-loop system. The boil-off gas is continuously compressed, cooled, and fed back into the tank, maintaining pressure stability while preventing fuel loss through automatic recovery.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

Instead of discarding the boil-off gas, the system recovers it by compressing and cooling the gas back to liquid form, then returning it to the storage tank. This recovery process eliminates fuel waste while maintaining tank pressure.

Inventive Principle:
Principle #34Discarding and recovering

3Loss of substance

If multistage compression and cooling is applied to reliquefy boil-off gas, then fuel recovery is improved, but system complexity increases

Engineering Contradiction:
Improveammonia fuel recoveryVSAvoidreliquefaction system complexity
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The patent segments the reliquefaction process into distinct stages: compression (first and second compressors), intermediate cooling (intercooler), and final condensation (condenser). Each stage handles a specific part of the thermodynamic transformation, making the complex process more manageable and efficient.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces an intercooler as an intermediary component between the compression and condensation stages. This intermediate cooling device removes heat from the compressed gas before it enters the condenser, improving the overall efficiency of the reliquefaction process and reducing the workload on subsequent cooling equipment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system reduces greenhouse gas emissions by reliquefying ammonia boil-off gas, preventing fuel waste, and maintains storage tank pressure, enhancing heat recovery efficiency and reducing installation costs while meeting stringent regulatory standards.

Implementation Method 1

a first compressor receiving and compressing boil-off gas generated from ammonia

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

a condenser cooling the boil-off gas compressed through the compression unit

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

wherein a temperature of the boil-off gas in the compression unit is adjusted by partially diverting the ammonia from the reliquefied gas recovery line to be supplied to the compression unit

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentEP4663531A1System and method for re-liquefying ammonia boil-off gas of vessel
Publication Date: 2025.12.17 HANWHA OCEAN CO LTD (KR)
  • EP4663531A1 patent drawingFigure 1
  • EP4663531A1 patent drawingFigure 2
  • EP4663531A1 patent drawing

AI summary

A system and method for reliquefaction of ammonia boil-off gas for ships is disclosed. The ammonia boil-off gas reliquefaction system includes: a compression unit for multistage compression of boil-off gas, the compression unit including a first compressor receiving and compressing boil-off gas generated from ammonia in a storage tank provided to a ship, and a second compressor further compressing the boil-off gas compressed in the first compressor; a condenser cooling the boil-off gas compressed through the compression unit; and a reliquefied gas recovery line along which ammonia cooled and condensed in the condenser is delivered to the storage tank, wherein a temperature of the boil-off gas in the compression unit is adjusted by partially diverting the ammonia from the reliquefied gas recovery line to be supplied to the compression unit.