System for improved hydrogen distribution in a metal hydride reactor

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional metal hydride reactors face issues with non-uniform hydrogen gas distribution, limited miniaturization, mechanical instability, and high production costs due to sintered tubes and low thermal conductivity of the metal/alloy powder bed.

Innovation Solution

A system with a metal wire mesh hydrogen distribution conduit within a metal tube, surrounded by a thermally conductive metal sponge matrix, allowing uniform hydrogen distribution and improved thermal conductivity, while maintaining mechanical stability and reducing reactor size and material requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If sintered tubes are used for hydrogen distribution, then hydrogen gas distribution is achieved, but miniaturization is restrained and reactor size increases

Engineering Contradiction:
Improvehydrogen distributionVSAvoidreactor size
Core Design Contradiction:
Ease of manufactureVSVolume of moving object

Solution Approach 1:

The patent replaces solid sintered tubes with a porous metal foam structure that allows hydrogen gas to permeate through its cellular structure. This porous material provides distribution functionality without the thickness constraints of sintered tubes, enabling smaller reactor diameters while maintaining effective hydrogen delivery to the metal hydride bed.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention uses a composite structure combining metal foam with traditional sintered powder bed. The metal foam acts as a distribution matrix that integrates both structural support and gas distribution functions, eliminating the need for separate thick-walled sintered tubes and enabling miniaturization.

Inventive Principle:
Principle #40Composite materials

2Strength

If sintered tubes with minimum thickness are used, then structural integrity is maintained, but weight reduction is limited

Engineering Contradiction:
Improvestructural integrityVSAvoidreactor weight
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The metal foam's cellular structure provides high strength-to-weight ratio, maintaining structural integrity through its three-dimensional network while significantly reducing material volume and weight compared to solid sintered tubes. The porous structure distributes mechanical loads effectively across its framework.

Inventive Principle:
Principle #31Porous materials

3Ease of manufacture

If sintered tubes are used for hydrogen distribution, then gas distribution is achieved, but production cost increases

Engineering Contradiction:
Improvehydrogen distributionVSAvoidraw material cost
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

Metal foam can be manufactured through cost-effective processes such as foam replication or direct foaming, eliminating the need for expensive sintering of thick-walled tubes. The material usage is optimized as the porous structure provides distribution functionality with minimal material volume, reducing both raw material costs and manufacturing expenses.

Inventive Principle:
Principle #31Porous materials

4Volume of moving object

If small diameter tubes are used, then reactor size is reduced, but mechanical stability decreases

Engineering Contradiction:
Improvereactor sizeVSAvoidmechanical stability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The metal foam's three-dimensional cellular network provides exceptional mechanical stability despite its small overall dimensions. The interconnected struts and cells distribute stresses uniformly throughout the structure, preventing the sagging and deformation issues that plague thin-walled small diameter tubes while maintaining the reduced reactor size.

Inventive Principle:
Principle #31Porous materials

5Quantity of substance

If metal/alloy powder bed with low thermal conductivity is used, then material requirements are met, but heat and mass transfer performance decreases

Engineering Contradiction:
Improvemetal/alloy powderVSAvoidheat and mass transfer rate
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The metal foam serves as a thermally conductive matrix that surrounds and contacts the metal hydride powder particles, creating a composite structure where the foam provides thermal pathways through its metallic continuity. This enhances heat transfer from the reaction sites without requiring additional metal/alloy powder, improving productivity while maintaining material efficiency.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances hydrogen sorption rates, reduces reactor size and production costs, and improves mechanical stability by ensuring uniform hydrogen distribution and increased thermal conductivity within the metal hydride reactor.

Implementation Method 1

The contact between the hydrogen distribution conduit and the metal sponge matrix is such that it provides for optimal hydrogen flow between them. The metal sponge matrix improves the thermal conductivity of the metal/alloy powder bed.

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

metals or alloys react with hydrogen exothermically to form metal hydrides

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

the metal hydrides reversibly release hydrogen gas endothermically

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 4

metals or alloys react with hydrogen exothermically to form metal hydrides

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 5

the metal hydrides reversibly release hydrogen gas endothermically

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Data Source

PatentUS10829369B2System for improved hydrogen distribution in a metal hydride reactor
Publication Date: 2020.11.10 THERMAX LTD (IN)
  • US10829369B2 patent drawing
  • US10829369B2 patent drawing
  • US10829369B2 patent drawing

AI summary

A system for distribution of hydrogen gas in a metal hydride reactor is disclosed. The system comprises a hydrogen distribution conduit positioned within a metal tube so as to define an annular space between the hydrogen distribution conduit and the outer metal tube. The hydrogen distribution conduit provides a flow passage for the hydrogen gas. A metal sponge matrix containing hydrogen-storing metal powder or hydrogen-storing alloy powder is filled in the annular space. The system provides a more uniform distribution of hydrogen across the particles of the hydrogen-storing metal/alloy powder, provides mechanical support to the hydrogen distribution conduit, improves the thermal conductivity of the powdered metal/alloy bed and reduces the size and production cost of the reactor.