Ta-C DLC Piston Ring Coating for Wear and Friction

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Solution Overview

Problem

Existing sliding elements, such as piston rings, face challenges in achieving a balance between wear resistance and low friction over their service life due to changes in DLC layer properties with layer thicknesses greater or less than 5 μm, leading to inadequate service life and friction losses.

Innovation Solution

A sliding element with a metal-containing adhesive layer and a ta-C DLC coating of at least 10 μm thickness, optimized through processes like metal ion sputtering and vacuum laser arc methods, ensuring adhesion and stress compensation, and featuring a specific composition and structure for improved wear and friction performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the DLC layer thickness is increased to improve wear resistance, then wear resistance is improved, but the layer properties change and service life is not achieved

Engineering Contradiction:
Improvewear resistanceVSAvoidservice life
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies a composite coating system consisting of a metal-containing adhesive layer (e.g., chromium, titanium, or their nitrides) combined with a ta-C DLC layer. This composite structure allows the adhesive layer to provide stress compensation and bonding to the substrate, while the ta-C layer provides wear resistance, enabling the DLC layer to be applied at optimal thicknesses (3-10 μm) without property degradation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition parameters by introducing metal-containing adhesive layers with specific properties (hardness, adhesion strength) and controlling the DLC layer composition (hydrogen-free or low-hydrogen, high sp3 content). These parameter changes enable the DLC layer to maintain its tribological properties at thicknesses greater than 5 μm by preventing property changes through proper stress management and bonding.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the DLC layer thickness is optimized for wear resistance, then wear resistance is improved, but friction losses increase

Engineering Contradiction:
Improvewear resistanceVSAvoidfriction losses
Core Design Contradiction:
StrengthVSLoss of energy

Solution Approach 1:

The patent optimizes the DLC layer parameters by producing hydrogen-free or low-hydrogen ta-C layers with high sp3 carbon content (at least 70%). This compositional parameter change maintains the low friction coefficient characteristic of ta-C while enabling the layer to achieve sufficient wear resistance at thicknesses of 3-10 μm, thus reducing both wear and friction losses simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If a thick DLC layer is applied to ensure service life, then durability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveservice lifeVSAvoidcoating system complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent segments the coating system into two distinct functional layers: a metal-containing adhesive layer (0.5-5 μm) and a ta-C DLC layer (3-10 μm). This segmentation allows each layer to be optimized for its specific function - the adhesive layer for bonding and stress management, and the DLC layer for wear and friction protection - enabling service life extension without excessive complexity in the coating application process.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides durable coatings with reduced wear and friction, achieving 60% less wear compared to hydrogen-containing DLC-coated piston rings, with improved thermal resistance and scuffing behavior under limited lubrication, and maintaining low friction throughout the engine's service life.

Implementation Method 1

the cleaning of the surface to be coated by a metal ion sputtering process

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 2

optimized through processes like metal ion sputtering and vacuum laser arc methods

Methodology Applied
Scientific EffectVacuum laser arc deposition: Pulsed Laser Deposition

Data Source

PatentEP3091100B1Sliding element, in particular a piston ring, having a coating and method for producing a sliding element
Publication Date: 2020.02.19 FEDERAL MOGUL BURSCHEID GMBH

AI summary

A sliding element, in particular a piston ring, has a coating on at least one running surface, from the inside out, consisting of a metal-containing adhesive layer and a DLC layer of type ta-C with a thickness of at least 10 µm. In a method for manufacturing a sliding element, in particular a piston ring, a coating with a metal-containing adhesive layer and a DLC layer of type ta-C with a thickness of at least 10 µm is applied.