Tackifier-Free Biodegradable Hot Melt Adhesive Composition

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Solution Overview

Problem

Conventional hot melt adhesives (HMAs) are not biodegradable, leading to environmental harm and are reliant on petrochemical-based components, which are not environmentally friendly.

Innovation Solution

A biodegradable hot melt adhesive is composed of a copolymer comprising a repeating unit of formula (Ia) and a repeating unit of formula (Ib) and polyvinyl alcohol (PVA), which eliminates the need for a separate tackifier, providing favorable adhesion, biodegradability, and properties such as setting time, open time, and softening point.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional hot melt adhesives are used, then favorable adhesion and setting properties are achieved, but biodegradability is poor and environmental harm occurs

Engineering Contradiction:
Improveenvironmental harmVSAvoidadhesion performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the adhesive by using biodegradable polymers (PLA, PCL, PHB) instead of conventional petrochemical polymers. This substitution maintains adhesion performance while improving biodegradability and reducing environmental harm.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive formulation combining multiple biodegradable polymer components (PLA, PCL, PHB) with specific ratios to achieve both favorable adhesion properties and biodegradability. The composite structure allows optimization of both performance and environmental compatibility.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If biodegradable polymers are used to improve environmental compatibility, then biodegradability increases, but adhesion performance may deteriorate

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidadhesion strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent formulates a composite system using biodegradable polymers (PLA, PCL, PHB) in specific combinations and ratios to achieve both biodegradability and adequate adhesion strength. The synergistic effect of multiple biodegradable components compensates for the lower individual adhesion performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes parameters such as polymer molecular weight, composition ratios, and processing conditions to enhance adhesion performance of biodegradable polymers while maintaining their biodegradable nature.

Inventive Principle:
Principle #35Parameter changes

3Strength

If tackifier is added to improve adhesion, then adhesion increases, but the formulation complexity and cost increase

Engineering Contradiction:
ImproveadhesionVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent removes the tackifier component from the adhesive formulation, relying instead on the inherent adhesion properties of the biodegradable polymer blend. This simplifies the formulation while maintaining acceptable adhesion performance for the intended applications.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive exhibits favorable adhesion, biodegradability, and desirable properties like setting time, open time, and softening point without the use of a tackifier, offering a cost-effective and environmentally friendly alternative to traditional HMAs.

Implementation Method 1

a copolymer comprising a repeating unit of formula (Ia) a repeating unit of formula (Ib) and one or more first C 2-10 -hydrocarbons each independently substituted with 2-6 substituents each independently selected from O and OH... and polyvinyl alcohol (PVA)

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

Biodegradable hot melt adhesives comprising a copolymer... It is well known that many conventional HMAs and polymers comprised therein are not biodegradable

Methodology Applied
Scientific EffectBiodegradation: Decomposition (biological)

Implementation Method 3

Hot melt adhesives (HMAs) are solid at room temperature and become liquid when heated above their softening point

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 4

After the application of the HMAs in molten stage, the HMAs wet the surface of the substrates

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentEP4466322B1Hot melt adhesive, method for the preparation and uses thereof
Publication Date: 2025.09.24 KIILTO
  • EP4466322B1 patent drawing
  • EP4466322B1 patent drawing
  • EP4466322B1 patent drawing

AI summary

Disclosed is a hot melt adhesive, a method for the preparation and uses thereof. More particularly, disclosed is a biodegradable hot melt adhesive comprising a copolymer, and polyvinyl alcohol (PVA).