TADF-TTA Dual-Layer Light Emitting Element for Efficiency and Service Life

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Solution Overview

Problem

There is a persistent demand for organic electroluminescence elements with low driving voltage, high luminous efficiency, and long service life in display devices, which existing technologies have not adequately addressed.

Innovation Solution

A light emitting element comprising a first emission layer with a (1-1)-th compound and a second emission layer with a (2-1)-th compound, where the (2-1)-th compound has a lowest excited triplet energy level of 1.5 eV to 2.1 eV, configured to emit fluorescence through thermally activated delayed fluorescence (TADF) and triplet-triplet annihilation (TTA), enhancing luminous efficiency and service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic electroluminescence materials are used, then the display device can achieve basic light emission, but the luminous efficiency and service life remain insufficient

Engineering Contradiction:
Improveluminous efficiencyVSAvoidservice life
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs a composite emission layer structure comprising a first emission layer with TADF material and a second emission layer with TTA material. This composite structure enables synergistic utilization of both delayed fluorescence and triplet-triplet annihilation mechanisms, achieving high luminous efficiency while extending service life through optimized energy utilization and reduced exciton quenching

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the triplet energy level parameter of the TTA material to be within 1.5 eV to 2.1 eV, and adjusts the thickness ratio between the first and second emission layers. These parameter optimizations enable efficient energy transfer from the TADF layer to the TTA layer, maximizing luminous efficiency while maintaining device stability and service life

Inventive Principle:
Principle #35Parameter changes

2Productivity

If phosphorescence emission or fluorescence with triplet-triplet annihilation is used, then luminous efficiency can be improved, but the device complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidemission layer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The emission layer is segmented into two functional sub-layers: a first emission layer containing TADF material for generating triplet excitons, and a second emission layer containing TTA material for converting triplet excitons to singlet excitons. This segmentation allows each layer to be optimized independently for its specific function while maintaining overall system simplicity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The dual-layer emission structure serves multiple functions: the first layer generates triplet excitons through TADF, the second layer converts triplet to singlet excitons through TTA, and the interface between layers facilitates efficient energy transfer. This multi-functionality achieves high luminous efficiency without proportionally increasing device complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed configuration improves luminous efficiency and service life of the light emitting element, resulting in enhanced display quality.

Implementation Method 1

configured to emit fluorescence through thermally activated delayed fluorescence (TADF)

Methodology Applied
Scientific EffectThermally activated delayed fluorescence (TADF): Fluorescence

Implementation Method 2

configured to emit fluorescence through thermally activated delayed fluorescence (TADF) and triplet-triplet annihilation (TTA)

Methodology Applied
Scientific EffectTriplet-triplet annihilation (TTA): Fluorescence

Data Source

PatentUS20250234776A1Light emitting element, and display device including the light emitting element
Publication Date: 2025.07.17 SAMSUNG DISPLAY CO LTD
  • US20250234776A1 patent drawing
  • US20250234776A1 patent drawing
  • US20250234776A1 patent drawing

AI summary

Embodiments provide a light emitting element and a display device that includes the light emitting element. The light emitting element includes a first electrode, a first emission layer disposed on the first electrode and including a (1-1)-th compound, a second emission layer disposed on the first emission layer and including a (2-1)-th compound, and a second electrode disposed on the second emission layer, wherein the (2-1)-th compound has a lowest excited triplet energy level (T1) in a range of about 1.5 eV to about 2.1 eV. The (1-1)-th compound is represented by Formula 1, the (2-1)-th compound is represented by Formula 2, and Formula 1 and Formula 2 are each described in the specification.