Tall-Oil Surfactant Defoaming Composition for Well Treatment Fluids

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Solution Overview

Problem

Traditional defoaming compositions in the oil and gas industry are ineffective in preventing foam formation and air entrainment in well treatment fluids, particularly with specific lubricating agents, leading to operational issues such as altered fluid density and viscosity, which can interfere with pumping and cement composition effectiveness.

Innovation Solution

A defoaming composition comprising a tall-oil-derived surfactant and a base oil, added to treatment fluids like drilling and cement compositions, effectively reduces foam by allowing trapped gas to escape, preventing further foam formation, and is suitable for a wide range of temperatures and fluid densities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional defoaming compositions are used, then they may function adequately to prevent foam formation during preparation and pumping, but they exhibit poor defoaming behavior in fluids with specific lubricating agents and cannot adequately break previously formed foam

Engineering Contradiction:
Improvedefoaming effectivenessVSAvoidcompatibility with lubricating agents
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent uses a composite defoaming composition combining silicone oil and a specific surfactant (alkyl polyglucoside or alkyl polyglycoside) to achieve both foam prevention and foam breaking capabilities. The silicone oil provides defoaming action while the surfactant enhances compatibility with lubricating agents and enables effective breaking of previously formed foam, resolving the contradiction between reliability and adaptability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameters by specifying particular surfactants (alkyl polyglucoside with 8-16 carbon atoms or alkyl polyglycoside with 12-24 carbon atoms) to improve defoaming effectiveness across different fluid conditions, particularly with lubricating agents present.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If foam or air is entrained into well treatment fluids during agitation, mixing and pumping, then the fluids can be processed, but the density change interferes with pump operation and fluid characteristics are altered

Engineering Contradiction:
Improvefluid processing capabilityVSAvoidfluid density
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The defoaming composition is added preliminarily during fluid preparation and pumping operations to prevent foam formation and air entrainment before they can significantly alter fluid density. This preliminary defoaming action maintains stable fluid characteristics throughout processing, resolving the contradiction between productivity and composition stability.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If foam is formed in well cement composition during pumping and mixing, then the cement can be placed, but the density reduction prevents desired hydrostatic pressure and compressive strength

Engineering Contradiction:
Improvecement placement capabilityVSAvoidcement compressive strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The defoaming composition is incorporated into the cement mixture preliminarily before pumping and placement to prevent foam formation. This ensures the cement maintains its required density for hydrostatic pressure and eventual compressive strength while remaining easy to pump and place, resolving the contradiction between ease of operation and strength.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves rapid defoaming, reducing foam index and entrained gas volume, ensuring stable fluid properties and operational efficiency, with a defoam time of 2-10 minutes, enhancing the performance of well treatment fluids during drilling and cementing operations.

Implementation Method 1

A defoaming composition comprising a tall-oil-derived surfactant and a base oil, added to treatment fluids like drilling and cement compositions, effectively reduces foam by allowing trapped gas to escape

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS10988672B2Defoaming composition comprising a tall-oil-derived surfactant
Publication Date: 2021.04.27 HALLIBURTON ENERGY SERVICES INC
  • US10988672B2 patent drawing

AI summary

The present disclosure may be directed to defoaming methods and compositions. A method of treating a subterranean formation may comprise providing a defoaming composition, wherein the defoaming composition comprises a tall-oil-derived surfactant. The method may further comprise mixing the defoaming composition with an aqueous fluid to form a treatment fluid such that foaming in the treatment fluid is reduced, wherein the treatment fluid is a water-based fluid. The method may further comprise placing the treatment fluid into the subterranean formation.