Tandem Cell Bottom-Cell Texturing for Optical Loss Reduction

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Solution Overview

Problem

Tandem solar cells suffer from significant optical loss and poor efficiency due to the combination of a top cell with a wide bandgap and a bottom cell with a narrow bandgap, limiting their performance.

Innovation Solution

The tandem cell design includes a bottom cell with a substrate featuring a first textured surface with larger protrusion structures and a micro textured surface with smaller protrusion structures, along with a conformal composite layer and top cell layers that enhance light reflection and reduce minority carrier recombination, ensuring uniform film layers and avoiding short circuits.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a tandem cell combines a top cell with wide bandgap and a bottom cell with narrow bandgap to break the single junction efficiency limit, then the theoretical photovoltaic conversion efficiency is improved, but significant optical loss occurs resulting in poor actual cell efficiency

Engineering Contradiction:
Improveoptical lossVSAvoidcell efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent applies surface texturing with protrusion structures to the substrate and conductive layer surfaces. These curved/rounded protrusion structures enhance light trapping and reflection, reducing optical loss by increasing the optical path length and improving light absorption in the tandem cell structure.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent modifies surface parameters by creating textured surfaces with specific protrusion structures at different scales. The substrate has a first textured surface with first protrusion structures, and the doped conductive layer has a micro textured surface with micro protrusion structures. These parameter changes in surface morphology reduce optical loss and improve light utilization.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If textured surfaces with protrusion structures are added to reduce optical loss, then light utilization is improved, but the device structure becomes more complex

Engineering Contradiction:
Improvelight utilizationVSAvoidstructure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the texturing into multiple levels: the substrate has a first textured surface with first protrusion structures, while the doped conductive layer has a micro textured surface with micro protrusion structures. This segmentation allows each layer to be optimized independently for light management while maintaining overall structural functionality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions and layers have different texturing characteristics. The substrate surface has first protrusion structures, the doped conductive layer has micro protrusion structures, and the composite layer is conformal to the micro textured surface. This local quality variation optimizes light interaction at different interfaces without requiring complex overall restructuring.

Inventive Principle:
Principle #3Local quality

3Reliability

If multiple layers including composite layer and conformal structures are added to reduce recombination and avoid short circuits, then reliability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecarrier recombination reductionVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The composite layer is formed conformally on the micro textured surface of the doped conductive layer before forming the top cell. This preliminary action of creating the conformal composite layer structure early in the manufacturing process establishes a foundation that guides subsequent layer formation, ensuring proper alignment and reducing recombination while simplifying later manufacturing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The composite layer merges the textured surface structure with the top cell formation process. By making the composite layer conformal to the micro textured surface, the patent combines light management functionality with structural integrity and electrical isolation functions in a single integrated layer, reducing the need for separate components.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design improves light utilization and photovoltaic conversion efficiency by enhancing light reflection and reducing recombination, leading to improved open circuit voltage and filling factor.

Implementation Method 1

The tandem cell design includes a bottom cell with a substrate featuring a first textured surface with larger protrusion structures and a micro textured surface with smaller protrusion structures, along with a conformal composite layer and top cell layers that enhance light reflection

Methodology Applied
Scientific EffectLight reflection: Reflection

Implementation Method 2

The solar cell uses the photovoltaic effect to generate carriers, which are then extracted using electrodes to be effectively utilized as electrical energy

Methodology Applied
Scientific EffectPhotovoltaic effect: Photovoltaic Effect

Implementation Method 3

the bottom cell further includes a tunneling dielectric layer formed on the second side

Methodology Applied
Scientific EffectQuantum tunneling:

Data Source

PatentUS12446389B2Tandem cell, method for preparing the same, and photovoltaic module
Publication Date: 2025.10.14 ZHEJIANG JINKO SOLAR CO LTD
  • US12446389B2 patent drawing
  • US12446389B2 patent drawing
  • US12446389B2 patent drawing

AI summary

The tandem cell includes a bottom cell including a substrate. The substrate has a first side and a second side, the first side has a first textured surface including at least one first protrusion structure. The bottom cell further includes a tunneling dielectric layer and a doped conductive layer. A surface of the doped conductive layer has a micro textured surface including at least one micro protrusion structure, and the micro protrusion structure is smaller than the first protrusion structure. The tandem cell further includes a composite layer conformal to the micro textured surface. The tandem cell further includes a top cell formed on the composite layer. The top cell includes a first transport layer, a perovskite substrate, a second transport layer, a transparent conductive layer, and an anti-reflection layer stacked sequentially. The first transport layer is conformal to the micro textured surface.