Targeted Oxygen Transport in Fuel Cell Electrodes

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Solution Overview

Problem

Fuel cells with reduced active catalyst material face efficiency issues due to poor oxygen transport to non-uniformly distributed catalyst particles, leading to inefficient fuel cell performance.

Innovation Solution

A method involving scanning and mapping active catalyst particles in the catalyst layer to create a gas diffusion layer with targeted gas distribution, using varying porosity and channel designs in carbon layers and plates to concentrate oxygen flow to areas with higher catalyst concentrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If the amount of active catalyst material is reduced to lower cost, then manufacturing cost decreases, but oxygen transport efficiency deteriorates

Engineering Contradiction:
Improvecatalyst material costVSAvoidfuel cell efficiency
Core Design Contradiction:
Loss of substanceVSProductivity

Solution Approach 1:

The gas diffusion layer is designed with spatially varying properties - regions with higher catalyst concentration receive higher gas flow rates and different porosity characteristics, while regions with lower catalyst concentration receive correspondingly adjusted gas distribution. This local customization of gas transport properties ensures efficient oxygen delivery to each catalyst particle regardless of overall catalyst loading, resolving the contradiction between reduced catalyst material and maintained fuel cell efficiency.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If uniform catalyst distribution is used, then manufacturing simplicity is maintained, but oxygen transport efficiency deteriorates due to non-uniform gas distribution

Engineering Contradiction:
Improvecatalyst layer fabrication simplicityVSAvoidoxygen transport efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The system performs preliminary mapping of the catalyst layer to detect and record the actual non-uniform distribution of catalyst particles before configuring the gas diffusion layer. This advance knowledge allows the gas diffusion layer to be pre-configured with appropriate spatial variations in porosity and gas flow channels that will compensate for the non-uniform catalyst distribution, ensuring efficient oxygen transport without requiring complex uniform catalyst fabrication.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If gas diffusion layer is configured to concentrate gas to detected catalyst particles, then oxygen transport improves, but device complexity increases

Engineering Contradiction:
Improveoxygen transport efficiencyVSAvoidgas diffusion layer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The gas diffusion layer utilizes controlled variations in physical parameters - primarily porosity and gas flow channel dimensions - to achieve targeted gas concentration at catalyst particle locations. By adjusting these parameters spatially according to the mapped catalyst distribution, the system achieves efficient oxygen delivery through relatively simple structural modifications rather than complex mechanical or chemical systems.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves oxygen transport and fuel cell efficiency by ensuring adequate oxygen supply to active catalyst sites, enhancing performance while minimizing catalyst material usage.

Implementation Method 1

forming a gas diffusion layer configured to concentrate gas distribution to the detected active catalyst particles based on the map

Methodology Applied
Scientific EffectGas diffusion: Diffusion

Implementation Method 2

forming a carbon layer having a gas distribution pattern configured to concentrate gas flow to the detected active catalyst particles based on the map

Methodology Applied
Scientific EffectPorosity-controlled flow: Porosity

Data Source

PatentUS10381654B2Methods of preparing electrodes having targeted oxygen transport
Publication Date: 2019.08.13 NISSAN MOTOR CO LTD
  • US10381654B2 patent drawing
  • US10381654B2 patent drawing
  • US10381654B2 patent drawing

AI summary

A method of preparing an electrode having targeted oxygen transport comprises applying a catalyst layer having active catalyst particles on a substrate, scanning the applied catalyst layer to detect the active catalyst particles in the catalyst layer, mapping the detected active catalyst particles, and forming a gas diffusion layer configured to concentrate gas distribution to the detected active catalyst particles based on the map.