Tempered Polyphenylene Sulfide Insulation for Vulcanized Heating Hoses

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Solution Overview

Problem

The vulcanization process of heatable articles, such as hoses, often results in a reduced or destroyed insulation layer due to heat and pressure, leading to 'braid imprints' and increased waste rates, as the insulation tears when the heating conductor is pulled out, compromising the electrical connection.

Innovation Solution

Using a polymeric sheathing material based on polyphenylene or its derivatives, specifically polyphenylene sulfide (PPS), which is tempered to enhance thermal resistance and adhesive strength, and embedding the tempered heating conductor in a vulcanizable polymer mixture for subsequent vulcanization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional polymeric insulation material is used during vulcanization, then the article can be manufactured, but the insulation layer is locally reduced or destroyed due to heat and pressure

Engineering Contradiction:
Improvevulcanization temperature resistanceVSAvoidinsulation layer integrity
Core Design Contradiction:
TemperatureVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from conventional polymeric insulation to polyphenylene-based insulation material, which has superior thermal stability and maintains its mechanical properties at vulcanization temperatures (130-200°C), preventing insulation layer destruction

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structure by combining polyphenylene-based polymer with the insulation layer, creating a material that resists both heat and pressure during vulcanization while maintaining insulation integrity and preventing braid imprint formation

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the heating conductor is pulled out after vulcanization, then electrical connection is enabled, but the insulation tears open due to braid imprints

Engineering Contradiction:
Improveelectrical connection accessibilityVSAvoidinsulation integrity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-tempering the polyphenylene-based insulation material before vulcanization, which stabilizes the material structure and prevents braid imprint formation, ensuring insulation integrity during subsequent conductor extraction and electrical connection

Inventive Principle:
Principle #10Preliminary action

3Strength

If polyphenylene-based material is used for sheathing, then thermal resistance and adhesive strength increase, but the material requires tempering treatment

Engineering Contradiction:
Improveadhesive strength to base bodyVSAvoidtempering process requirement
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by implementing a tempering process that heats the polyphenylene-based sheathing material to specific temperatures and holds it there, which modifies the material's crystalline structure and achieves the desired adhesive strength and thermal resistance properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces waste rates and ensures the heating conductor can be exposed for electrical connection without damage, maintaining insulation integrity and increasing the strength of the heatable article.

Implementation Method 1

the sheathing is a polymeric material based on a polyphenylene or a polyphenylene derivative, the polymeric material being tempered

Methodology Applied
Scientific EffectHeat treatment (tempering): Heat Treatment

Implementation Method 2

The heating conductor comprises a metallic core and a sheath as an insulating layer... In order to heat a medium flowing in the hose

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentEP2214176B1Heatable item, in particular a heatable hose, with a plastic clad heat conductor and method for producing same
Publication Date: 2011.10.26 CONTITECH SCHLAUGH GMBH
  • EP2214176B1 patent drawingFigure 1~3

AI summary

The article has an elastic base body made up of vulcanized rubber, where a heating conductor (1) is embedded in the base body. The heating conductor is electrically connected to an electrical connection device. The heating conductor includes an inner cover (2) as a heating wire, and a sheath (3) made of electrically insulating polymer material. The polymer material is selected from a group consisting of polyphenylene, polyphenylene oxide, polyphenylene sulfide and polyphenylene ether, where the polymer material is tempered. An independent claim is also included for a method for manufacturing a heatable article.