Ternary Chalcogenide Thin Films for Flexible Electronics

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Solution Overview

Problem

Current electrically conductive thin films for flexible electronic devices face challenges in achieving high conductivity and transparency while maintaining flexibility, as materials like ITO have limitations due to indium scarcity, poor flexibility, and low conductivity.

Innovation Solution

Development of a flexible electrically conductive thin film with a ternary chalcogenide compound having a layered crystal structure, such as NbPdTe5 or TaPtTe5, which provides high conductivity and transparency, exceeding 80% light transmittance and exceeding 1000 S/cm electrical conductivity, using materials like V, Nb, or Ta with metals like Ni, Co, or Pd, and chalcogens like Te, S, or Se.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If indium tin oxide (ITO) is used for electrically conductive thin films, then electrical conductivity is improved, but material availability deteriorates due to limited reserves of indium

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmaterial availability
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the material composition parameters by replacing indium-based compounds with alternative materials such as aluminum-doped zinc oxide (AZO), tin-doped indium oxide (ITO) with reduced indium content, or other transparent conductive oxides that maintain electrical conductivity while reducing dependence on scarce indium resources

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures by combining multiple elements (e.g., aluminum and zinc in AZO, or creating multi-layer structures) to achieve the desired electrical conductivity and optical properties without relying heavily on indium, thus resolving the contradiction between conductivity and material availability

Inventive Principle:
Principle #40Composite materials

2Reliability

If indium tin oxide (ITO) is used for electrically conductive thin films, then electrical conductivity is improved, but flexibility deteriorates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent develops flexible thin film structures with reduced thickness and optimized composition (such as AZO or ITO with lower indium content) that maintain electrical conductivity while achieving the mechanical flexibility required for bendable and foldable electronic devices

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent modifies physical parameters including film thickness, composition ratios, and deposition conditions to create conductive layers that are both electrically functional and mechanically flexible, enabling application in next-generation flexible electronics

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If oxide materials like tin oxide or zinc oxide are used, then flexibility is improved, but electrical conductivity deteriorates

Engineering Contradiction:
ImproveflexibilityVSAvoidelectrical conductivity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent creates composite oxide materials by doping zinc oxide with aluminum (AZO) or combining multiple oxide layers, where the composite structure achieves both the flexibility of oxide materials and the enhanced electrical conductivity needed for functional electrodes in flexible devices

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS9767936B2Electrically conductive thin films
Publication Date: 2017.09.19 SAMSUNG ELECTRONICS CO LTD
  • US9767936B2 patent drawing
  • US9767936B2 patent drawing
  • US9767936B2 patent drawing

AI summary

An electrically conductive thin film including a compound represented by Chemical Formula 1 and having a layered crystal structure:AxMyChz  Chemical Formula 1wherein A is V, Nb, or Ta, M is Ni, Co, Fe, Pd, Pt, Ir, Rh, Si, or Ge, Ch is S, Se, or Te, x is a number from 1 to 3, y is a number from 1 to 3, and z is a number from 2 to 14.