Ternary Deep Eutectic Solvent for Chitin Extraction

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Solution Overview

Problem

Current methods for extracting chitin from seafood waste are inefficient and environmentally harmful, often requiring harsh chemicals that lead to waste effluents and high water consumption.

Innovation Solution

A ternary deep eutectic solvent (TDES) system comprising a hydrogen bond acceptor (HBA), a polyol-based hydrogen bond donor (HBD), and an organic acid HBD is used to extract high-purity chitin from seafood waste, with adjustable molecular weight and viscosity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional methods are used to extract chitin from seafood waste, then chitin can be recovered, but harsh chemicals are required leading to environmental harm and high water consumption

Engineering Contradiction:
Improveenvironmental harmVSAvoidextraction efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent changes the chemical parameters of the extraction system by using a ternary deep eutectic solvent system composed of choline chloride, lactic acid, and glycerol in specific molar ratios. This parameter change allows for effective chitin extraction without harsh chemicals, reducing environmental harm while maintaining extraction efficiency through the unique solvent properties of the TDES system

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite solvent system combining three components (choline chloride, lactic acid, and glycerol) to create a ternary deep eutectic solvent. This composite material approach enables synergistic effects where the combination of components provides enhanced extraction capability while being environmentally friendly, resolving the contradiction between efficiency and environmental harm

Inventive Principle:
Principle #40Composite materials

2Loss of substance

If conventional extraction methods are used, then chitin can be extracted, but high water consumption is required

Engineering Contradiction:
Improvewater consumptionVSAvoidextraction capability
Core Design Contradiction:
Loss of substanceVSProductivity

Solution Approach 1:

The patent replaces water-based mechanical extraction systems with a chemical solvent system (ternary deep eutectic solvent). This substitution eliminates the need for large volumes of water while maintaining effective chitin extraction through the solvent's chemical interactions with chitin molecules, thereby reducing water consumption without sacrificing extraction capability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If the TDES system is used to extract chitin, then high purity and tunable molecular weight are achieved, but the system complexity increases

Engineering Contradiction:
Improvemolecular weight controlVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent achieves molecular weight control by adjusting the molar ratios of the TDES components (choline chloride, lactic acid, and glycerol). By changing these parameters, the solvent system can be tuned to extract chitin with specific molecular weights, enabling precise control over product properties without requiring complex equipment or multiple processing stages

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The TDES system enables efficient and environmentally friendly extraction of chitin with high purity and tunable molecular weight, reducing the need for harsh chemicals and minimizing waste generation.

Implementation Method 1

a hydrogen bond acceptor (HBA) such as betaine or choline chloride (CC), a polyol-based hydrogen bond donor (HBD) such as glycerol, and an organic acid HBD such as ascorbic acid, citric acid, lactic acid, malic acid

Methodology Applied
Scientific EffectHydrogen bonding:

Data Source

PatentUS20250188199A1Ternary deep eutectic solvent system and uses thereof
Publication Date: 2025.06.12 UNIV OF CONNECTICUT
  • US20250188199A1 patent drawing
  • US20250188199A1 patent drawing
  • US20250188199A1 patent drawing

AI summary

A ternary deep eutectic solvent (TDES) system for a biomolecule (for example, chitin) recovery from a biomass (for example, seafood waste), and the method of preparation of ternary deep eutectic solvent (TDES) system, and a process to differentiate/extract/recover biomolecules (such as chitin) from a biomass (such as seafood waste).