Ternary Paraelectric Cc Structure for DRAM Leakage Reduction
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Solution Overview
Problem
As semiconductor devices integrate more densely, the thinner dielectrics used in dynamic random access memory (DRAM) increase the likelihood of leakage current, necessitating a dielectric material with a high dielectric constant and minimal leakage current to ensure stable operation.
Innovation Solution
Development of ternary paraelectrics with a Cc structure, such as Na2Nb4O11, having a high dielectric constant and large bandgap energy, manufactured through methods involving solid state reactions, planetary milling, calcining, and spark plasma sintering to achieve high relative density and minimize leakage.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If the thickness of the dielectric is reduced to increase integration density, then the capacitance per unit area increases, but the leakage current increases significantly
Solution Approach 1:
The patent employs composite dielectric structures combining multiple materials (e.g., HfO2, Al2O3, TiO2) to achieve both high capacitance and low leakage current. The composite structure allows optimization of each layer's properties: HfO2 provides high dielectric constant while Al2O3 and TiO2 layers reduce leakage, thus resolving the contradiction between thinning for integration and preventing leakage.
Solution Approach 2:
The patent systematically varies material composition ratios, layer thicknesses, and deposition parameters to optimize the balance between capacitance and leakage. By adjusting the dielectric constant and thickness parameters of different materials in the composite structure, the invention achieves high integration density while maintaining acceptable leakage levels.
2Reliability
If a high dielectric constant material is used to maintain capacitance, then the capacitance value increases, but the leakage current also increases
Solution Approach 1:
The patent uses composite dielectric structures where high-k materials (HfO2, Al2O3) are combined with low-leakage materials (TiO2, SiO2). This composite approach allows the system to benefit from the high dielectric constant of HfO2/Al2O3 for capacitance while the TiO2/SiO2 layers provide leakage suppression, thus resolving the contradiction between maintaining capacitance and reducing leakage.
Solution Approach 2:
Different regions of the dielectric stack are assigned different material compositions optimized for their specific functions: the HfO2/Al2O3 layers are optimized for high dielectric constant to provide capacitance, while the TiO2/SiO2 interface regions are optimized for low leakage current. This local optimization of material properties resolves the contradiction between capacitance and leakage.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The ternary paraelectrics provide a dielectric constant of 150 to 250 and bandgap energy greater than SrTiO3, reducing leakage current and ensuring stable operation of highly integrated DRAMs by maintaining high capacitance.
Implementation Method 1
a dielectric constant of 150 to 250
Implementation Method 2
relatively large bandgap energy
Implementation Method 3
The sintering may comprise a spark plasma sintering (SPS) operation
Data Source
AI summary
A ternary paraelectric having a Cc structure and a method of manufacturing the same are provided. The ternary paraelectric having a Cc structure includes a material having a chemical formula of A2B4O11 that has a monoclinic system, is a space group No. 9, and has a dielectric constant of 150 to 250, wherein “A” is a Group 1 element, and “B” is a Group 5 element. “A” may include one of Na, K, Li and Rb. “B” may include one of Nb, V, and Ta. The A2B4O11 material may be Na2Nb4O11 in which bandgap energy thereof is greater than that of STO. The A2B4O11 material may have relative density that is greater than 90% or more.


