Ternary Paraelectric Cc Structure for DRAM Leakage Reduction

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Solution Overview

Problem

As semiconductor devices integrate more densely, the thinner dielectrics used in dynamic random access memory (DRAM) increase the likelihood of leakage current, necessitating a dielectric material with a high dielectric constant and minimal leakage current to ensure stable operation.

Innovation Solution

Development of ternary paraelectrics with a Cc structure, such as Na2Nb4O11, having a high dielectric constant and large bandgap energy, manufactured through methods involving solid state reactions, planetary milling, calcining, and spark plasma sintering to achieve high relative density and minimize leakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the thickness of the dielectric is reduced to increase integration density, then the capacitance per unit area increases, but the leakage current increases significantly

Engineering Contradiction:
Improveintegration densityVSAvoidleakage current
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent employs composite dielectric structures combining multiple materials (e.g., HfO2, Al2O3, TiO2) to achieve both high capacitance and low leakage current. The composite structure allows optimization of each layer's properties: HfO2 provides high dielectric constant while Al2O3 and TiO2 layers reduce leakage, thus resolving the contradiction between thinning for integration and preventing leakage.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically varies material composition ratios, layer thicknesses, and deposition parameters to optimize the balance between capacitance and leakage. By adjusting the dielectric constant and thickness parameters of different materials in the composite structure, the invention achieves high integration density while maintaining acceptable leakage levels.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a high dielectric constant material is used to maintain capacitance, then the capacitance value increases, but the leakage current also increases

Engineering Contradiction:
Improvecapacitance stabilityVSAvoidleakage current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses composite dielectric structures where high-k materials (HfO2, Al2O3) are combined with low-leakage materials (TiO2, SiO2). This composite approach allows the system to benefit from the high dielectric constant of HfO2/Al2O3 for capacitance while the TiO2/SiO2 layers provide leakage suppression, thus resolving the contradiction between maintaining capacitance and reducing leakage.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Different regions of the dielectric stack are assigned different material compositions optimized for their specific functions: the HfO2/Al2O3 layers are optimized for high dielectric constant to provide capacitance, while the TiO2/SiO2 interface regions are optimized for low leakage current. This local optimization of material properties resolves the contradiction between capacitance and leakage.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ternary paraelectrics provide a dielectric constant of 150 to 250 and bandgap energy greater than SrTiO3, reducing leakage current and ensuring stable operation of highly integrated DRAMs by maintaining high capacitance.

Implementation Method 1

a dielectric constant of 150 to 250

Methodology Applied
Scientific EffectDielectric constant: Dielectric Permittivity

Implementation Method 2

relatively large bandgap energy

Methodology Applied
Scientific EffectBandgap energy: Electrical Resistance

Implementation Method 3

The sintering may comprise a spark plasma sintering (SPS) operation

Methodology Applied
Scientific EffectSpark plasma sintering: Spark Plasma Sintering

Data Source

PatentUS20250206633A1Ternary paraelectric material with space group cc and method of manufacturing the same
Publication Date: 2025.06.26 SAMSUNG ELECTRONICS CO LTD
  • US20250206633A1 patent drawing
  • US20250206633A1 patent drawing
  • US20250206633A1 patent drawing

AI summary

A ternary paraelectric having a Cc structure and a method of manufacturing the same are provided. The ternary paraelectric having a Cc structure includes a material having a chemical formula of A2B4O11 that has a monoclinic system, is a space group No. 9, and has a dielectric constant of 150 to 250, wherein “A” is a Group 1 element, and “B” is a Group 5 element. “A” may include one of Na, K, Li and Rb. “B” may include one of Nb, V, and Ta. The A2B4O11 material may be Na2Nb4O11 in which bandgap energy thereof is greater than that of STO. The A2B4O11 material may have relative density that is greater than 90% or more.