Ternary Refrigerant Blend for Low-GWP R-134a Replacement

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Solution Overview

Problem

Current refrigerants like R-410A and R-134a have high Global Warming Potential (GWP) and ozone depletion potential, necessitating the search for alternatives that are environmentally friendly and efficient in refrigeration and air conditioning systems.

Innovation Solution

Ternary compositions of 2,3,3-tetrafluoropropene, 1,1-difluoroethane, and difluoromethane are used as heat transfer fluids, offering zero ODP and GWP below existing fluids, with improved performance and compatibility with existing compressor technologies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If HFC-134a is used as refrigerant, then ozone depletion is reduced, but global warming potential increases

Engineering Contradiction:
Improveozone depletionVSAvoidglobal warming potential
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by using a ternary mixture of HFO-1234yf, HFC-32, and HFC-152a instead of conventional HFC-134a, achieving both low GWP and acceptable refrigeration performance through optimized compositional parameters

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If carbon dioxide is used as refrigerant, then global warming potential is reduced, but pressure requirements increase

Engineering Contradiction:
Improveglobal warming potentialVSAvoidpressure requirements
Core Design Contradiction:
Object-generated harmful factorsVSStress or pressure

Solution Approach 1:

The patent creates a composite refrigerant system by combining three different compounds (HFO-1234yf, HFC-32, and HFC-152a) in specific proportions, achieving a balance between environmental performance and operational pressure characteristics that neither pure substance could achieve alone

Inventive Principle:
Principle #40Composite materials

3Productivity

If R-410A is used as refrigerant, then cooling performance is improved, but global warming potential increases

Engineering Contradiction:
Improvecooling performanceVSAvoidglobal warming potential
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the compositional parameters of the ternary mixture to achieve cooling performance comparable to R-410A while maintaining GWP below 150, specifically by adjusting the ratios of HFO-1234yf, HFC-32, and HFC-152a to balance thermodynamic properties with environmental constraints

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10035938B2Heat transfer fluid replacing R-134a
Publication Date: 2018.07.31 ARKEMA FRANCE SA
  • US10035938B2 patent drawing
  • US10035938B2 patent drawing

AI summary

A heat transfer method using ternary composition containing 2,3,3,3-tetrafluoropropene, 1,1-difluoroethane and difluoromethane, as a heat transfer fluid in refrigeration systems, to replace R-134a. 1. A method of modifying a heat transfer system containing R-134a comprising removing R-134a and adding a composition comprising a refrigerant consisting essentially of: 70 to 88 wt % of 2,3,3,3-tetrafluoropropene; 4 to 16 wt % of difluoromethane; 8 to 14 wt % of 1,1-difluoroethane; and optionally, a stabilizer.