Terpene Resin Solvent-Based Inkjet Formulation for Long Throw

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Solution Overview

Problem

Thermal inkjet printing faces challenges with poor image quality due to inadequate throw distance and reliability issues, particularly when printing on complex substrates, and suffers from short decap times leading to printhead clogging.

Innovation Solution

Inkjet inks formulated with a terpene resin and a solvent system comprising a ketone solvent with a boiling point below 120°C and dioxolane, which enhance decap time and allow printing at long throw distances up to 15 mm.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If thermal inkjet printing is used with conventional ink formulations, then high print resolution at lower cost is achieved, but throw distance is limited to 1-2 mm resulting in poor image quality on complex substrates

Engineering Contradiction:
Improveimage qualityVSAvoidthrow distance
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The patent modifies the physical and chemical parameters of the ink formulation, specifically using a terpene resin binder with a solvent system containing ketone and dioxolane in controlled ratios. This changes the ink's volatility, surface tension, and drying characteristics to enable stable jetting at extended throw distances of 5-15 mm while maintaining image quality on complex substrates

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite ink formulation by combining terpene resin with a specific solvent mixture of ketone (30-70 wt%) and dioxolane (10-40 wt%). This composite material structure provides the unique properties needed to overcome the throw distance limitation of conventional thermal inkjet inks while maintaining reliability and image quality

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional solvent-based inkjet inks are used, then acceptable decap times are achieved, but printhead clogging occurs after prolonged exposure to air

Engineering Contradiction:
Improvedecap timeVSAvoidprinthead clogging
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent adjusts the volatility parameters of the solvent system by selecting ketone and dioxolane with specific boiling points and evaporation rates. This creates an optimized balance where the ink remains stable in the printhead for extended decap times (preventing clogging) while still drying quickly after application to complex substrates, thereby improving reliability without sacrificing performance

Inventive Principle:
Principle #35Parameter changes

3Reliability

If ink formulations are optimized for long decap times, then reliability improves, but throw distance performance deteriorates

Engineering Contradiction:
Improvedecap timeVSAvoidthrow distance
Core Design Contradiction:
ReliabilityVSLength of moving object

Solution Approach 1:

The patent performs multi-parameter optimization of the ink formulation, adjusting the resin type, solvent composition, and their ratios to achieve a balanced performance profile. The specific combination of terpene resin with ketone (30-70 wt%) and dioxolane (10-40 wt%) creates an ink that simultaneously achieves extended decap times for reliability and sufficient throw distance (5-15 mm) for complex substrate printing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops a composite ink system where the interaction between terpene resin and the dual-solvent system (ketone + dioxolane) creates synergistic effects. This composite formulation achieves both long decap times and extended throw distance performance, resolving the trade-off between reliability and throw distance capability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink formulation provides extended decap times and enables high-quality printing on complex substrates with improved reliability and image clarity at extended throw distances.

Implementation Method 1

a solvent system that includes (B1) a ketone solvent having a boiling point of less than 120 °C and (B2) dioxolane

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

the print cartridges contain a series of tiny chambers, each containing a heater, which produce ink droplets from thermal vaporization of an ink solvent

Methodology Applied
Scientific EffectThermal vaporization: Phase Change

Data Source

PatentEP4326827B1Solvent-based inkjet inks
Publication Date: 2025.09.03 KAO CORP
  • EP4326827B1 patent drawingFigure 1
  • EP4326827B1 patent drawingFigure 2
  • EP4326827B1 patent drawing

AI summary

An inkjet ink that includes (A1) a terpene resin, and (B) a solvent system containing (B1) a ketone solvent having a boiling point of less than 120 °C and (B2) dioxolane, the inkjet ink being characterized by extended decap times and long throw distance. A printed article including the inkjet ink in dried form, and a method of forming a printed image with a thermal inkjet printhead are also provided.