Tertiary Amine UV-Curable Adhesive for Optical Laminates

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional UV curable adhesives fail to achieve sufficient curing and adhesive strength when attaching optical layers with both UV permeable and impermeable regions to UV impermeable substrates, due to insufficient ultraviolet radiation reaching the UV impermeable regions.

Innovation Solution

An adhesive composition comprising a (meth)acrylate monomer, a photocurable (meth)acrylate oligomer, a photoinitiator, and a tertiary amine compound, which allows for effective curing of both UV permeable and impermeable regions by stabilizing radicals and ensuring thorough curing even in UV impermeable areas.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional UV curable adhesives are used to attach optical layers with UV impermeable regions, then the UV permeable regions can be cured, but the UV impermeable regions remain insufficiently cured resulting in low adhesive strength

Engineering Contradiction:
Improveadhesive strengthVSAvoidUV light penetration
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the adhesive by incorporating a tertiary amine compound (specifically a polyalkylene glycol derivative with amino groups) alongside the photoinitiator. This compositional parameter change enables the adhesive to cure through both UV irradiation and thermal activation, allowing sufficient curing in UV impermeable regions while maintaining proper curing in UV permeable regions, thereby achieving reliable adhesive strength across the entire optical layer.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If heating is applied after UV irradiation to cure adhesive in UV impermeable regions, then adhesive curing is improved, but the substrate may be damaged

Engineering Contradiction:
Improveadhesive curingVSAvoidsubstrate damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The tertiary amine compound acts as a chemical intermediary that enables dual-curing mechanisms. It absorbs UV energy to initiate radical polymerization in UV permeable regions, and simultaneously undergoes thermal polymerization in UV impermeable regions when exposed to heat from the UV lamp or ambient conditions. This intermediary substance allows the adhesive to cure completely without requiring excessive external heating that could damage the substrate, as the tertiary amine itself generates the necessary thermal reaction locally.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Use of energy by moving object

If UV light is irradiated to cure the adhesive, then UV permeable regions are cured, but insufficient ultraviolet rays reach the adhesive under UV impermeable regions

Engineering Contradiction:
ImproveUV light curingVSAvoidcured area
Core Design Contradiction:
Use of energy by moving objectVSArea of stationary object

Solution Approach 1:

The adhesive composition is designed with multi-functionality to respond to multiple energy inputs. The photoinitiator component handles UV curing for UV permeable regions, while the tertiary amine compound component handles thermal curing for UV impermeable regions. This universal formulation ensures that the entire adhesive layer, regardless of its position relative to UV impermeable regions, achieves complete curing through the combined action of both curing mechanisms, maximizing the effective cured area.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive composition ensures excellent adhesive strength for attaching optical layers with both UV permeable and impermeable regions to UV impermeable substrates, enhancing the reliability of touch sensors and other optical laminates.

Implementation Method 1

a UV curable adhesive... curing of the adhesive must proceed by irradiating UV light... a photoinitiator

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

a tertiary amine compound... stabilizing radicals and ensuring thorough curing even in UV impermeable areas

Methodology Applied
Scientific EffectRadical stabilization:

Data Source

PatentUS10836931B2Adhesive composition and optical laminate using the same
Publication Date: 2020.11.17 DONGWOO FINE CHEM CO LTD
  • US10836931B2 patent drawing
  • US10836931B2 patent drawing
  • US10836931B2 patent drawing

AI summary

An adhesive composition includes a (meth)acrylate monomer, a photocurable (meth)acrylate oligomer, a photoinitiator and a tertiary amine compound. Also, an optical laminate includes an adhesive layer formed of the adhesive composition. The adhesive composition can attach an optical layer simultaneously including a UV permeable region and a UV impermeable region onto a UV impermeable substrate with excel lent adhesive strength.