Textile Bluing Composition for Yellowing Without Blue Build-Up

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Solution Overview

Problem

Textile articles experience visually-perceived yellow coloration due to repeated use and laundering, with existing solutions failing to effectively address this issue without causing excessive build-up or staining.

Innovation Solution

A bluing composition concentrate containing specific blue or violet colorants, conforming to certain structural formulas, is used in an aqueous treatment to deposit onto textiles, counteracting yellow coloration without excessive build-up, comprising an aqueous medium, a primary colorant with specific solubility and deposition characteristics, and optionally secondary colorants, with minimal surfactant content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional bluing agents are used to decrease yellow coloration, then the yellow coloration is reduced, but excessive blue build-up occurs with successive treatments

Engineering Contradiction:
Improveyellow colorationVSAvoidblue build-up
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The patent modifies the chemical structure of the bluing agent by specifying particular ratios of aromatic rings to sulfonate groups, and by defining the nature of substituent groups (R1-R6), to achieve optimal deposition characteristics that prevent excessive build-up while maintaining effectiveness against yellow coloration

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific structural variations at different positions of the bluing agent molecule (different R groups at positions R1-R6) to create localized chemical properties that control deposition behavior and prevent uniform excessive build-up across the textile surface

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If conventional bluing agents are used to decrease yellow coloration, then the yellow coloration is reduced, but excessive staining occurs

Engineering Contradiction:
Improveyellow colorationVSAvoidstaining
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent adjusts chemical parameters including the number of aromatic rings (a+d and b+e values), the nature of substituent groups, and the counterion type to optimize the balance between color correction effectiveness and staining prevention

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If high surfactant content is used in bluing composition, then deposition on textile is enhanced, but excessive build-up and staining increase

Engineering Contradiction:
Improvecolorant depositionVSAvoidexcessive build-up and staining
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes surfactant concentration to a specific range (0.1-5 wt% in concentrate, less than 25 ppm in diluted composition) to achieve sufficient wetting and deposition promotion while avoiding the harmful effects of excessive surfactant that lead to build-up and staining

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite bluing composition integrating the specifically structured colorant with controlled amounts of surfactant and aqueous medium, where the synergistic interaction between components achieves effective deposition without excessive build-up

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces visually-perceived yellow coloration on textiles without causing excessive blue build-up, maintaining aesthetic quality and stability through controlled deposition and lightfastness, as demonstrated by improved Δb* values and reduced lightfastness loss compared to commercial products.

Implementation Method 1

the textile article to absorb at least a portion of the bluing composition

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentEP2427539B1Bluing composition and method for treating textile articles using the same
Publication Date: 2016.11.09 MILLIKEN & CO
  • EP2427539B1 patent drawing
  • EP2427539B1 patent drawing
  • EP2427539B1 patent drawing

AI summary

A bluing composition concentrate comprises an aqueous medium and at least one colorant that exhibits a blue or violet shade when deposited onto a textile material. The concentrate can be used to produce a bluing composition, and the bluing composition can be used to treat textile materials in such a way as to decrease the visually-perceived yellow coloration of textile articles that can occur with repeated use and laundering.