Textile Coating with Bilayer Polymers to Reduce Bacterial Adhesion

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Solution Overview

Problem

Biological adhesion of bacteria such as Staphylococcus aureus (S. aureus) and Pseudomonas aeruginosa to textiles used in medical and athletic applications leads to undesirable infections and odors, with existing solutions like metal-based bactericidal agents facing issues of resistance and environmental toxicity.

Innovation Solution

Application of a polymeric coating comprising bilayers of cationic and anionic polymers, such as PDDA and PAA, using layer-by-layer deposition, which reduces bacterial adhesion without killing the bacteria, thereby minimizing the risk of antimicrobial resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal-based bactericidal agents are incorporated into textiles, then bacterial adhesion is reduced, but bacteria develop immunity and the textile loses effectiveness over time

Engineering Contradiction:
Improvebacterial adhesion resistanceVSAvoidtextile effectiveness duration
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the mechanism of action from bactericidal (killing bacteria) to anti-adhesion (preventing bacteria from attaching). This parameter change in the mode of action prevents bacteria from developing immunity while maintaining long-term effectiveness. The coating creates a physical barrier that bacteria cannot adhere to, rather than relying on chemical bactericidal action that bacteria can resist.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite coating system comprising multiple layers including at least one biologically active agent layer and at least one other functional layer. This composite structure provides both anti-adhesion properties and durability, with the biologically active agent preventing bacterial attachment while the composite structure ensures long-term effectiveness through multiple functional layers working together.

Inventive Principle:
Principle #40Composite materials

2Reliability

If metal bactericidal agents are incorporated into textiles, then bacterial adhesion is reduced, but metal may wear away or be washed out over time

Engineering Contradiction:
Improvebacterial adhesion resistanceVSAvoidbactericidal agent retention
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent applies a thin film coating to the textile surface that provides anti-adhesion properties without the wear and washing out problems of incorporated metal agents. The coating forms a flexible barrier layer that remains intact on the textile surface, preventing bacterial adhesion while being resistant to wear and washing.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent introduces a coating layer as an intermediary between the bacteria and the textile. This intermediate layer provides the anti-adhesion function while protecting the underlying textile from direct contact with bacteria and preventing the coating materials from wearing away or washing out.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If metal bactericidal agents are incorporated into textiles, then bacterial adhesion is reduced, but environmental toxicity increases

Engineering Contradiction:
Improvebacterial adhesion resistanceVSAvoidenvironmental toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates the toxic metal components from the textile treatment while retaining the desired anti-adhesion function. By removing the harmful metal bactericidal agents and replacing them with non-toxic coating materials, the solution maintains bacterial adhesion resistance without environmental toxicity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the approach from using harmful substances (metal bactericidal agents) to using beneficial or neutral substances (non-toxic coating materials). The harm of metal toxicity is eliminated while the benefit of bacterial adhesion resistance is maintained through alternative mechanisms.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Reliability

If a coating is applied to reduce bacterial adhesion, then bacterial adhesion is reduced, but coating thickness increases

Engineering Contradiction:
Improvebacterial adhesion resistanceVSAvoidcoating thickness
Core Design Contradiction:
ReliabilityVSLength of stationary object

Solution Approach 1:

The patent employs thin film coatings that provide effective anti-adhesion properties with minimal thickness. The coating is designed as a thin barrier layer that prevents bacterial attachment while maintaining a low profile and not significantly increasing the overall dimensions of the textile.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating effectively reduces bacterial adhesion by at least 95% and maintains this effectiveness after washing, significantly reducing the risk of bacterial infections and odors on treated textiles.

Implementation Method 1

a coating comprising a plurality of bilayers positioned one on top of the other, wherein each bilayer comprises a first layer comprising a cationic polymer and a second layer comprising an anionic polymer

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Data Source

PatentEP3585934B1Coatings for materials
Publication Date: 2025.05.28 TEXAS A&M UNIVERSITY
  • EP3585934B1 patent drawingFigure 1A
  • EP3585934B1 patent drawingFigure 1B
  • EP3585934B1 patent drawingFigure 2A

AI summary

A textile includes a substrate and a coating applied to a surface of the substrate. The coating includes a plurality of bilayers positioned one on top of the other. Each bilayer includes a first layer including a cationic polymer and a second layer comprising an anionic polymer. The cationic polymer in the first layer includes a polyethyleneimine (PEI), a poly(vinyl amine) (PVAm), a poly(allyl amine) (PAAm), a polydiallyldimethylammonium chloride (PDDA), or a chitosan (CH). The anionic polymer in the second layer includes a poly(acrylic acid) (PAA), a poly(styrene sulfonate) (PSS), a poly(methacrylic acid) (PMAA), a poly(sodium phosphate) (PSP), or a poly(vinyl sulfate) (PVS).