Textile Printing Ink Set for Dye Fixation Without Color Bleeding

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Solution Overview

Problem

Existing textile printing methods face challenges in preventing color staining and bleeding of inks on other textiles, particularly with the use of cationic polymers which can lead to undesirable migration of dyes during washing.

Innovation Solution

A textile printing ink set comprising a pretreatment liquid with a cationic compound of specific molecular weight and a water-insoluble dye, along with a dispersing agent, applied using an ink jet process to ensure strong fixation of the dye on the textile, reducing the likelihood of color staining and bleeding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cationic polymers are used for textile printing, then dye fixation is achieved, but color staining and bleeding occur on other textiles

Engineering Contradiction:
Improvedye fixationVSAvoidcolor staining and bleeding
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the molecular weight parameter of the cationic polymer from conventional high molecular weight to specifically 10,000 to 200,000, which optimizes the balance between dye fixation capability and prevention of color migration. This parameter adjustment allows the polymer to effectively bind dyes while reducing their tendency to stain or bleed onto other textiles.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite system consisting of a cationic polymer with specific molecular weight characteristics combined with water-insoluble dyes. This composite approach creates a synergistic effect where the polymer provides fixation while its controlled molecular structure prevents excessive binding that would cause staining, thereby resolving the contradiction between effective fixation and preventing harmful color transfer.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If pretreatment liquid is applied before ink to obtain sharp images, then image quality improves, but process complexity increases

Engineering Contradiction:
Improveimage sharpnessVSAvoidprinting process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent combines the pretreatment liquid application and ink printing into an integrated inkjet printing system. The pretreatment liquid is applied first to prepare the textile surface for sharp image formation, and then the ink is applied in the same printing process, merging two steps into a coordinated sequence that maintains image quality while managing process complexity through integration.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively minimizes color transfer to other textiles and bleeding by ensuring strong dye fixation, enhancing the durability and cleanliness of printed textiles.

Implementation Method 1

a pretreatment liquid including a cationic compound having a molecular weight per cationic valence of 150 to 220

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

an ink composition including a water-insoluble dye, a dispersing agent, and water

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 3

the dispersing agent is at least one selected from the group consisting of a urethane resin, a urea resin, and a urethane-urea resin

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 4

applying the ink composition included in the ink set according to any one of <1> to 9>, to the textile to which the pretreatment liquid has been applied

Methodology Applied
Scientific EffectAerosol: Aerosol

Data Source

PatentUS11952502B2Textile printing ink set and textile printing method
Publication Date: 2024.04.09 FUJIFILM CORP
  • US11952502B2 patent drawing
  • US11952502B2 patent drawing
  • US11952502B2 patent drawing

AI summary

Provided are a textile printing ink set including a pretreatment liquid including a cationic compound having a molecular weight per cationic valence of 150 to 220, and an ink composition including a water-insoluble dye, a dispersing agent, and water, wherein the dispersing agent is at least one selected from the group consisting of a urethane resin, a urea resin, and a urethane-urea resin; and a textile printing method.