Near Neutral Buoyancy Textured Additive for Electrodeposition

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Solution Overview

Problem

Existing electrodeposition coating methods lack the ability to create textured coatings with low gloss and high texture on complex-shaped substrates, particularly for military applications where both texture and reduced gloss are desired without using traditional flatting pigments.

Innovation Solution

A method involving the electrodepositing of a composition comprising a textured additive with a density of no more than 4.5 g/cc and a melting point greater than the curing temperature, combined with a film-forming resin, to achieve a textured coating layer with a degree of texture of at least 250μ-in on coated surfaces, while maintaining a low gloss finish of 60° or less, using a single electrodeposition application step.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If traditional flatting pigments are used to reduce gloss, then gloss is reduced, but texture is not achieved and coating uniformity deteriorates

Engineering Contradiction:
ImproveglossVSAvoidcoating uniformity
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The invention removes traditional flatting pigments from the coating composition and replaces them with a textured additive consisting of hollow microspheres. This extraction eliminates the harmful side effects of flatting pigments while achieving the desired low gloss appearance through the physical texture created by the microspheres, thereby maintaining coating uniformity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the physical parameters of the coating system by introducing hollow microspheres with specific density (0.01-4.5 g/cc) and size ranges. These parameter changes create surface texture that reduces gloss while maintaining coating uniformity, avoiding the use of traditional flatting pigments that compromise uniformity.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If textured additives with high density are used, then texture is achieved, but the additives sink during electrodeposition and texture uniformity deteriorates

Engineering Contradiction:
Improvetexture uniformityVSAvoidadditive suspension stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The invention uses hollow microspheres with low density (0.01-4.5 g/cc) that provide buoyancy to counteract gravitational settling. The hollow structure creates an anti-weight effect that keeps the textured additives suspended uniformly throughout the coating composition during electrodeposition, preventing sinking and ensuring consistent texture distribution.

Inventive Principle:
Principle #8Anti-weight (Counterweight)

Solution Approach 2:

The invention optimizes the density parameter of the textured additive by using hollow microspheres with density between 0.01-4.5 g/cc. This parameter change ensures the additives remain suspended during electrodeposition while still providing sufficient surface texture, achieving both texture uniformity and compositional stability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If a single electrodeposition step is used, then productivity is improved, but achieving both texture and low gloss simultaneously becomes difficult

Engineering Contradiction:
Improvecoating application efficiencyVSAvoidsurface finish quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention merges multiple functions into a single textured additive component: hollow microspheres that provide both surface texture for low gloss appearance and suspension stability for uniform deposition. This consolidation allows texture and low gloss to be achieved simultaneously in a single electrodeposition step, maintaining high productivity while ensuring surface finish quality.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses a composite textured additive consisting of hollow microspheres combined with the coating resin. This composite material provides both the physical texture needed for low gloss and the chemical properties needed for stable suspension and uniform electrodeposition, enabling simultaneous achievement of texture and surface finish quality in one coating step.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the successful application of a textured, low-gloss coating on complex-shaped substrates, including military applications, with consistent texture and reduced gloss across all coated surfaces, enhancing durability and aesthetic appeal without the need for traditional flatting pigments.

Implementation Method 1

the textured additive has a density (specific gravity) of no more than 4.5 g/cc

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Implementation Method 2

Electrodeposition as a coating application method involves the deposition onto a conductive substrate of a film-forming composition under the influence of an applied electrical potential

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Implementation Method 3

a melting point greater than a curing temperature of said electrodepositable coating composition

Methodology Applied
Scientific EffectThermal stability:

Data Source

PatentUS8845873B2Near neutral buoyancy texture additive for electrodepositable coating compositions and associated methods for forming textured coated substrates
Publication Date: 2014.09.30 PPG INDUSTRIES OHIO INC

AI summary

Disclosed herein are electrodepositable coating compositions comprising a film forming resin and a textured additive, wherein the textured additive has a density (specific gravity) of no more than 4.5 g/cc and a melting point greater than the curing temperature of the electrodepositable coating composition. Also described are coated substrates having a cured coating layer comprising the electrodepositable coating composition, wherein the cured film layer has a texture of at least 250μ-in as measured by a profilometer at conventional cured film thicknesses.