3D Textured Silicon Anode With LMOF-SPE Cell for Higher Capacity

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current energy storage devices, particularly lithium batteries, face challenges in achieving high energy and power density while being miniaturized for IoT and other applications, requiring improved energy capacity and manufacturing processes to lower costs.

Innovation Solution

The development of a lithium manganese oxyfluoride (LMOF) cathode combined with a solid polymer electrolyte (SPE) and a textured silicon substrate created using laser ablation, which enhances the surface area and adhesion, leading to improved charge storage and reduced internal resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If lithium metal electrode material is integrated to achieve high theoretical specific capacity, then energy capacity is improved, but device miniaturization and manufacturing complexity worsen

Engineering Contradiction:
Improveenergy capacityVSAvoidmanufacturing complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent employs porous silicon substrate with high surface area to volume ratio, allowing increased lithium insertion sites while maintaining compact device form factor. The porous structure enables high energy capacity through enhanced lithium storage capability without proportionally increasing device volume, thus resolving the contradiction between energy capacity and device miniaturization.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent uses composite materials including silicon-germanium alloy and carbon-coated silicon particles combined with conductive polymers and binders. These composite structures improve manufacturing feasibility by enhancing structural stability, reducing volume expansion issues, and improving electrical conductivity, thereby addressing the manufacturing complexity associated with pure lithium metal integration.

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If device miniaturization is implemented to meet IoT requirements, then device size is reduced, but energy density requirements increase

Engineering Contradiction:
Improvedevice sizeVSAvoidenergy density
Core Design Contradiction:
Volume of moving objectVSQuantity of substance

Solution Approach 1:

The porous silicon substrate provides extremely high surface area to volume ratio, enabling increased lithium insertion capacity within a compact volume. This allows the battery to achieve high energy density (more lithium stored per unit volume) while maintaining miniaturized device dimensions, directly resolving the contradiction between device size reduction and energy density requirements.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent transitions from traditional planar electrode structures to three-dimensional porous architectures. This dimensional change enables volumetric optimization where the porous network fills space efficiently, providing numerous lithium insertion pathways and sites within the available volume, thereby achieving high energy density in miniaturized devices.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Area of stationary object

If textured surface is created by laser ablation to enhance adhesion, then surface area is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvesurface areaVSAvoidmanufacturing process complexity
Core Design Contradiction:
Area of stationary objectVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical texturing methods with laser ablation technology. The laser process directly writes the textured pattern onto the silicon substrate through photothermal ablation, eliminating the need for multiple mechanical machining steps, tooling fixtures, and post-processing operations. This substitution maintains high surface area for adhesion while significantly simplifying the manufacturing process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes controllable laser parameters (power, pulse duration, scanning speed, wavelength) to directly generate the desired surface texture. By adjusting these parameters, the same laser system can produce various texturing patterns and depths without changing physical tooling or process equipment, thereby achieving high surface area while keeping manufacturing complexity low through parameter optimization rather than process complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in increased battery capacity, reduced internal resistance, and sustainable energy storage with enhanced performance and longevity, suitable for miniaturized devices.

Implementation Method 1

the textured active area is created by laser ablation

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS11961958B23D textured composite silicon anode and fluorinated lithium compound electrochemical cell
Publication Date: 2024.04.16 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US11961958B2 patent drawing
  • US11961958B2 patent drawing
  • US11961958B2 patent drawing

AI summary

A composition includes an electrode made of Lithium Manganese Oxyfluoride (LMOF). A single layer separator adheres to a surface of the electrode, is a dielectric that is conductive for Lithium ions but not electrons, and has top and bottom sides. A solid polymer electrolyte (SPE) saturates the electrode so that the LMOF is between 55 percent and 85 percent by mass of a composition of the LMOF electrode and the SPE is between 7.5 percent and 20 percent by mass of the composition of the LMOF electrode. The SPE saturates the separator so that the SPE resides both on the separator top and bottom sides so that the SPE residing on the separator top side contacts the surface. The LMOF exhibits X-Ray Diffraction spectrum peaks between twenty-two and twenty-four 2-theta degrees, between forty-eight and fifty 2-theta degrees, between fifty-four and fifty-six 2-theta degrees, and between fifty-six and fifty-eight 2-theta degrees.