Thin-Film Transistor Active Layer with Carbon Allotropes

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Solution Overview

Problem

Current thin-film transistors in display devices face challenges in achieving optimal electron mobility, leakage current, and on/off ratio, with materials like amorphous silicon offering low electron mobility, oxide semiconductors having low electron mobility and high leakage current, and polycrystalline silicon being expensive for large-area applications.

Innovation Solution

A thin-film transistor array substrate is developed with an active layer comprising a semiconductor material and carbon allotropes, where the carbon allotrope content is higher near the gate electrode and decreases further away, utilizing reduced graphene oxide, non-oxidized graphene, or carbon nanotubes, to enhance electron mobility and maintain a high on/off ratio.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If amorphous silicon is used as the active layer material, then the production cost is low and the film-forming process is simple, but the electron mobility is as low as 0.5 cm²/Vs

Engineering Contradiction:
Improvefilm-forming process simplicityVSAvoidelectron mobility
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent uses a composite active layer comprising oxide semiconductor and carbon allotrope. The carbon allotrope (graphene, carbon nanotube, or full C60) is mixed with the oxide semiconductor at specific ratios (0.1-10 wt%) to create a composite material that combines the low-cost, easy-to-form properties of oxide semiconductor with the high electron mobility of carbon allotrope, achieving electron mobility of 10-100 cm²/Vs while maintaining manufacturing simplicity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameter by introducing carbon allotrope into the oxide semiconductor matrix. This parameter change transforms the electrical properties of the active layer, increasing electron mobility from 0.5 cm²/Vs (pure amorphous silicon) to 10-100 cm²/Vs (composite material) while maintaining the low-temperature processing advantages

Inventive Principle:
Principle #35Parameter changes

2Reliability

If oxide semiconductor is used as the active layer material, then the electron mobility can be improved, but the leakage current is high

Engineering Contradiction:
Improveelectron mobilityVSAvoidleakage current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent creates a composite active layer where carbon allotrope is dispersed in oxide semiconductor. The carbon allotrope forms conductive pathways that improve electron mobility while the oxide semiconductor matrix maintains insulating properties to suppress leakage current, achieving a balance between the two opposing requirements

Inventive Principle:
Principle #40Composite materials

3Reliability

If polycrystalline silicon is used as the active layer material, then the electron mobility is high, but the production cost is high for large-area applications

Engineering Contradiction:
Improveelectron mobilityVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive polycrystalline silicon with a cheaper alternative: oxide semiconductor combined with small amounts of carbon allotrope. This substitution achieves comparable or superior electron mobility (10-100 cm²/Vs) at lower cost, making large-area display manufacturing economically viable

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the material composition from pure polycrystalline silicon to a composite of oxide semiconductor + carbon allotrope, altering the electrical properties to achieve high electron mobility through the carbon allotrope's unique electronic structure while maintaining cost-effectiveness

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves electron mobility and maintains a stable threshold voltage, balancing the trade-offs between electron mobility and on/off ratio, while being cost-effective for large-area applications.

Implementation Method 1

an active layer comprising a first active layer, which opposes the gate electrode and is adjacent to the gate electrode thereby comprising a semiconductor material and a plurality of carbon allotropes

Methodology Applied
Scientific EffectElectron conduction through carbon allotropes: Conduction (electrical)

Data Source

PatentEP3301724B1Thin-film transistor and display device
Publication Date: 2020.11.11 LG DISPLAY CO LTD
  • EP3301724B1 patent drawingFigure 1~2
  • EP3301724B1 patent drawingFigure 3~4
  • EP3301724B1 patent drawingFigure 5~6

AI summary

A carbon allotrope and a display device including the same are disclosed. The thin-film transistor array substrate, comprising a substrate, a gate electrode on the substrate, an active layer comprising a first active layer, which opposes the gate electrode and is adjacent to the gate electrode thereby comprising a semiconductor material and a plurality of carbon allotropes, and a second active layer, which is in contact with the first active layer and comprises a semiconductor material, a gate insulating film between the gate electrode and the active layer, and a source electrode and a drain electrode respectively in contact with the active layer.