TFT Metal Catalyst Gettering via Source Drain Electrodes

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Solution Overview

Problem

Existing methods for crystallizing amorphous silicon into polycrystalline silicon for thin film transistors (TFTs) face issues such as long processing times, substrate deformation, high costs, and contamination from metal catalysts, leading to degraded device characteristics and increased leakage current.

Innovation Solution

A bottom-gate TFT is fabricated using a metal catalyst layer, where the channel region is gettered using the source/drain electrode material layer as a gettering site, with a second metal or its silicide diffused into the semiconductor layer under the electrodes to reduce metal catalyst presence, thereby improving electrical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a metal catalyst is used to crystallize the a-Si layer, then the crystallization temperature is reduced and processing time is shortened, but metal catalyst contamination remains in the poly-Si layer causing increased leakage current

Engineering Contradiction:
Improvecrystallization processing timeVSAvoidmetal catalyst contamination
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts the harmful metal catalyst from the channel region by introducing a gettering site that selectively absorbs and traps the metal catalyst, separating the beneficial crystallization function from the harmful contamination effect

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces a gettering site as an intermediary element between the metal catalyst and the channel region, which mediates the interaction by capturing the metal catalyst before it can contaminate the active device area

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If a conventional gettering process is performed using impurities or additional a-Si layers, then some metal catalyst removal is attempted, but the metal catalyst is not effectively removed and leakage current remains large

Engineering Contradiction:
Improvemetal catalyst contaminationVSAvoidleakage current
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent employs the source/drain electrode material layer to serve dual functions: as the electrical contact structure and as the gettering site for metal catalyst removal, eliminating the need for separate gettering structures

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent merges the source/drain electrode function with the gettering function into a single integrated structure, combining electrical connectivity with contamination removal capabilities

Inventive Principle:
Principle #5Merging (Combining)

3Stability of the object's composition

If the a-Si layer is annealed at high temperature for long period (SPC method), then the a-Si layer is crystallized into poly-Si, but the substrate is deformed and processing time is excessive

Engineering Contradiction:
Improvecrystallization of a-Si layerVSAvoidannealing time
Core Design Contradiction:
Stability of the object's compositionVSDuration of action of stationary object

Solution Approach 1:

The patent changes the crystallization parameters by using metal catalyst-assisted crystallization at lower temperatures and shorter times, fundamentally altering the thermal processing conditions from high-temperature long-duration to low-temperature short-duration

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If the gettering site is located far from the channel region, then the fabrication process is simplified, but the effectiveness of metal catalyst removal is reduced

Engineering Contradiction:
Improvegettering site placementVSAvoidmetal catalyst removal efficiency
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent positions the gettering site in a spatially optimal location adjacent to the channel region, utilizing the vertical and lateral dimensions effectively to maximize metal catalyst capture while maintaining fabrication simplicity

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces metal catalyst contamination in the channel region, enhancing the electrical properties of the TFT and reducing leakage current, while simplifying the fabrication process and avoiding substrate deformation.

Implementation Method 1

A channel region of a semiconductor layer, which is crystallized using a metal catalyst layer, is gettered using a source/drain electrode material layer as a gettering site

Methodology Applied
Scientific EffectGettering: Gettering

Implementation Method 2

A second metal, or a silicide of the second metal, is diffused into a surface region of the semiconductor layer, under the source and drain electrodes, to a predetermined depth

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

a metal, such as nickel (Ni), palladium (Pd), gold (Au), or aluminum (Al), is brought into contact with, or doped into, an a-Si layer to induce a phase change of the a-Si layer into a poly-Si layer

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS7999261B2Thin film transistor, method of fabricating the same, and organic light emitting diode display device having the TFT
Publication Date: 2011.08.16 SAMSUNG DISPLAY CO LTD
  • US7999261B2 patent drawing
  • US7999261B2 patent drawing
  • US7999261B2 patent drawing

AI summary

A thin film transistor (TFT), a method of fabricating the same, and an organic light emitting diode (OLED) display device having the TFT, the TFT including a substrate, a gate electrode disposed on the substrate, a gate insulating layer disposed on the gate electrode, a semiconductor layer disposed on the gate insulating layer and crystallized using a metal catalyst, and source and drain electrodes disposed on the semiconductor layer and electrically connected to source and drain regions of the semiconductor layer. A second metal is diffused into a surface region of the semiconductor layer, to getter the metal catalyst from a channel region of the semiconductor layer. The second metal can have a lower diffusion coefficient in silicon than the metal catalyst.