Thermal Boil-Off Gas Compression for Cryogenic Hydrogen Storage

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The generation of boil off gas during the withdrawal of cryogenic fluids from storage tanks increases tank pressure, necessitating energy-intensive and costly atmospheric release or compression, which is inefficient and environmentally harmful.

Innovation Solution

A method utilizing a cryogenic pump, vaporizer, and thermally driven compressor to compress and store boil off gas in a buffer tank, leveraging the temperature differential of the cryogenic fluid for energy-efficient operation, without additional power or connections.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If boil off gas is released to atmosphere, then tank pressure is reduced, but energy is wasted and greenhouse effect increases

Engineering Contradiction:
Improveenergy wasteVSAvoidgreenhouse effect
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The invention converts the harmful boil-off gas that would normally be released to atmosphere into a useful resource by compressing it and storing it in a buffer tank. The gas is no longer waste but a storable product, eliminating both energy waste and greenhouse effect while maintaining tank pressure control.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention changes the pressure parameter of the boil-off gas by using a compressor to increase its pressure from tank pressure to buffer tank pressure. This parameter change enables the gas to be stored in a different phase and location, transforming it from a harmful release into a useful stored resource.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If thermally driven compressor is used, then energy consumption is reduced, but device complexity increases

Engineering Contradiction:
Improveenergy consumptionVSAvoiddevice complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The thermally driven compressor uses heat from the cryogenic fluid itself as the driving energy source, making the system self-sufficient. The heat exchange between the cold cryogenic fluid and the warmer compressor mechanism provides the thermal energy needed for compression without external power input, reducing energy consumption while accepting increased device complexity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Reduces energy consumption and operational costs while preventing atmospheric release of boil off gas, particularly effective for hydrogen storage by utilizing the waste energy from the liquefaction process.

Implementation Method 1

The vaporizer can be, for example an atmospheric or ambient vaporizer that causes the liquid cryogenic fluid to be vaporized by heat exchange with ambient air

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

The compressor is a thermally driven compressor, i.e., a compressor that uses a cold source and a hot source, i.e., two sources of different temperature, for operation

Methodology Applied
Scientific EffectThermal compression: Thermal Expansion

Implementation Method 3

In an embodiment, a metal hydride compressor is used as said thermally driven compressor. Such metal hydride compressor is working on the principle of reversible absorption and desorption of hydrogen in a metal hydride driven by two heat sources

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 4

boil off gas is generated due to heat input, cooling down of the pump and friction

Methodology Applied
Scientific EffectFriction heating: Friction

Data Source

PatentEP4582732A1Method for removing boil off gas when storing cryogenic fluid and corresponding system
Publication Date: 2025.07.09 CRYOSTAR
  • EP4582732A1 patent drawingFigure 1
  • EP4582732A1 patent drawingFigure 2a
  • EP4582732A1 patent drawingFigure 2b

AI summary

The invention relates to a method for removing boil off gas when storing cryogenic fluid (H2) in a storage tank (110), wherein a cryogenic pump (130) is used to pump fluid from the storage tank (110), in a liquid phase, to a vaporizer (140), wherein, in the vaporizer (140), the fluid is vaporized and provided in a gaseous phase, wherein the boil off gas is provided to a thermally driven compressor (120), and compressed by the thermally driven compressor (120), and wherein the thermally driven compressor (120) is operated using part of the fluid, in the liquid phase from before the vaporizer (140) as cold source (122), and using at least part of the fluid, in the gaseous phase from after the vaporizer as hot source (124).