Thermal Reagent Flow Detection for Chlorine Analyzer Reliability

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Solution Overview

Problem

Existing online chlorine analyzers face challenges in ensuring simultaneous and proper delivery of reagents, such as DPD buffer and indicator, to the measurement cell, which is crucial for accurate chlorine detection in water samples, as issues like empty bottles, clogged tubing, and improper ratios can lead to unreliable measurements.

Innovation Solution

A reagent delivery subsystem that includes a cartridge with heating elements and thermal sensing elements to detect fluid flow, ensuring that both reagents are delivered simultaneously and in the correct ratio by applying a thermal pulse to the fluid lines and monitoring the temperature downstream, thereby verifying proper reagent delivery before each measurement cycle.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thermal pulse detection method is implemented to verify reagent delivery, then reliability of chlorine detection is improved, but device complexity increases due to additional heating elements and thermal sensors

Engineering Contradiction:
Improvereliability of chlorine detectionVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The system performs a preliminary thermal pulse test before the actual chlorine measurement to verify reagent delivery. A heating element applies a known thermal pulse to the fluid line, and thermal sensors detect the temperature change to confirm reagent flow. This preliminary verification ensures reliable reagent delivery before the critical measurement step.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces thermal energy as an intermediary to verify reagent delivery. Instead of directly measuring reagent presence, the system uses a heating element to apply thermal energy and thermal sensors to detect its propagation through the reagent stream. This intermediary thermal signal serves as a reliable indicator of proper reagent flow.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If multiple reagents are delivered simultaneously in proper ratios, then measurement precision is improved, but ease of operation deteriorates due to difficulty in ensuring simultaneous and proper ratio delivery

Engineering Contradiction:
Improvemeasurement precisionVSAvoidease of operation
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The system incorporates feedback through thermal sensors that monitor reagent delivery in real-time. The sensors detect the thermal pulse generated by the heating element and provide feedback signals to the controller. Based on this feedback, the system can verify that reagents are being delivered simultaneously in the correct ratios, ensuring measurement precision while automating the verification process.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent replaces manual verification of reagent delivery with an automated thermal detection system. Instead of relying on mechanical flow meters or manual checks, the system uses thermal energy propagation through the reagent stream to automatically verify delivery conditions. This substitution simplifies operation while maintaining precise control over reagent delivery.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution effectively detects the presence and proper flow of reagents, preventing errors due to empty bottles or occlusions, ensuring reliable chlorine detection in water samples by confirming simultaneous and adequate reagent delivery, thus enhancing the accuracy and trustworthiness of chlorine concentration measurements.

Implementation Method 1

operate the at least one heating element to produce heating of the at least one fluid line

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

operate the at least one heat sensing element to detect the heat of a fluid within the at least one fluid line

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentEP3479078B1Heat transfer based gas flow detector and online analyzer for chlorine
Publication Date: 2021.01.27 HACH
  • EP3479078B1 patent drawingFigure 1
  • EP3479078B1 patent drawingFigure 2
  • EP3479078B1 patent drawingFigure 3

AI summary

An embodiment provides an apparatus, including: a cartridge including a base and a lid; at least one fluid line located between the base and the lid of the cartridge; at least one heating element located either on the base or the lid and aligned in intimate contact with the at least one fluid line; at least one heat sensing element in intimate contact with the at least one fluid line, where the at least one heat sensing element is spaced downstream from the at least one heating element; a supply of power to the cartridge; and a processor in electrical communication with the cartridge that executes a program of instructions to: operate the at least one heating element to produce heating of the at least one fluid line at a first position; and operate the at least one heat sensing element to detect the heat of a fluid within the at least one fluid line at a position downstream of the first position. Other embodiments are described and claimed