Thermal Silicone Paste Composition for Heat Transfer and Pump-Out Resistance

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Solution Overview

Problem

Existing heat conductive materials face challenges in achieving high thermal conductivity, ease of working, and improved slide resistance, particularly in electronic devices where heat dissipation is critical.

Innovation Solution

A heat conductive silicone composition comprising a crosslinked silicone gel, a specific silicone oil, an aluminum powder with a specific particle size distribution, a zinc oxide powder, and a volatile solvent, such as isoparaffin, which enhances thermal conductivity and resistance to pump-out phenomena.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If sheet-like heat conductive materials are used, then ease of handling and stability are improved, but heat dissipation ability deteriorates due to increased contact thermal resistance

Engineering Contradiction:
Improveease of handlingVSAvoidheat dissipation ability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention changes the physical state parameter of the heat conductive material from solid sheet to paste form, enabling better conformability to surfaces and reduced contact thermal resistance while maintaining ease of application through controlled viscosity parameters

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If sheet-like materials are used, then shape stability is improved, but adaptability to device tolerance deteriorates and stress concentration increases

Engineering Contradiction:
Improveshape stabilityVSAvoidadaptability to tolerance
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The invention uses a paste-like material that can deform and conform to irregular surfaces and tolerance variations, providing flexible adaptation while maintaining structural integrity through proper formulation

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If paste-like heat conductive materials are used, then heat dissipation ability and adaptability are improved, but slide resistance deteriorates due to pump-out phenomenon

Engineering Contradiction:
Improveheat dissipation abilityVSAvoidslide resistance
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention creates a composite paste material combining heat conductive fillers with a specifically formulated silicone resin base, achieving both high thermal conductivity and improved slide resistance through the synergistic effects of the composite structure

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the viscosity parameter of the paste material to balance spreadability during application with resistance to pump-out during thermal cycling, using controlled rheological properties to prevent migration

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If low viscosity paste is used for mass-scale manufacture, then ease of application is improved, but slide resistance deteriorates causing pump-out phenomenon

Engineering Contradiction:
Improveease of applicationVSAvoidslide resistance
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The invention precisely controls the viscosity parameter within an optimal range, ensuring the paste is fluid enough for easy screen printing and applicator deposition while maintaining sufficient body to resist gravitational and thermal cycling-induced migration

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves high thermal conductivity while improving ease of working and pump-out resistance, ensuring effective heat removal and preventing device malfunction.

Implementation Method 1

a volatile solvent, especially isoparaffin base solvent having a boiling point of 80-360°C

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a heat conductive silicone composition comprising (A) a crosslinked silicone gel, (B) a silicone oil... (C) an aluminum powder... (D) a zinc oxide powder

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentEP4050068B1Thermally conductive silicone composition and production method therefor
Publication Date: 2025.01.29 SHIN ETSU CHEMICAL CO LTD
  • EP4050068B1 patent drawing
  • EP4050068B1 patent drawing
  • EP4050068B1 patent drawing

AI summary

A thermally conductive silicone composition that has high thermal conductivity and excellent workability and misalignment resistance, and contains, in specific ratios: a silicone gel cross-linked product (A); a silicone oil (B) not containing either aliphatic unsaturated bonds or SiH groups and being used as a surface treatment agent for components (C) and (D); an aluminum powder (C) including (C-1)-(C-3), (C-1) being an aluminum powder having an average particle diameter of 40-100 µm, (C-2) being an aluminum powder having an average particle diameter of at least 6 µm and less than 40 µm, and (C-3) being an aluminum powder having an average particle diameter of at least 0.4 µm and less than 6 µm; a zinc oxide powder (D) having an average particle diameter of 0.1-10 µm; and a volatile solvent (E).