Thermally Conductive Polymer Compositions for Miniaturized Electronics

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Solution Overview

Problem

There is a need for thermally conductive polymer compositions that provide superior heat dissipation while retaining the properties of laser direct structuring, strength, and flow, which is essential for the miniaturization of portable electronic devices where heat retention degrades performance.

Innovation Solution

The development of blended thermoplastic compositions comprising 50 wt% to 95 wt% of polyamide polymers, 4 wt% to 49.95 wt% of high thermally conductive fillers with thermal conductivity greater than or equal to 50 W/mK, and 0.05 wt% to 20 wt% of laser direct structuring additives, achieving through-plane thermal conductivity of at least 0.40 W/mK and a plating index value of at least 0.4.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If device dimensions are reduced for miniaturization, then device size decreases, but heat retention increases degrading performance

Engineering Contradiction:
Improvedevice sizeVSAvoidheat retention
Core Design Contradiction:
Volume of moving objectVSTemperature

Solution Approach 1:

The patent employs composite polymer compositions incorporating thermally conductive fillers (such as aluminum nitride, boron nitride, aluminum oxide, silicon carbide, graphite, or carbon fiber) within a polyamide matrix. These composite materials achieve thermal conductivities ranging from 0.4 to 25 W/mK, enabling effective heat dissipation in miniaturized electronic devices while maintaining the compact form factor required for modern portable electronics.

Inventive Principle:
Principle #40Composite materials

2Temperature

If thermally conductive fillers are added to polymer compositions, then thermal conductivity increases, but laser direct structuring capability may be affected

Engineering Contradiction:
Improvethermal conductivityVSAvoidlaser direct structuring capability
Core Design Contradiction:
TemperatureVSAdaptability or versatility

Solution Approach 1:

The patent incorporates laser direct structuring (LDS) additives at specific concentrations (0.05 to 20 wt%) within the thermally conductive polymer composition. These LDS additives are strategically distributed to enable selective laser activation and metal plating in specific regions, while the bulk material maintains its thermal conductivity properties through the dispersed fillers. This local quality approach allows simultaneous achievement of thermal management and customizable conductive pathway formation.

Inventive Principle:
Principle #3Local quality

3Temperature

If high loading of thermally conductive fillers is used, then thermal conductivity improves, but mechanical properties and flow characteristics may deteriorate

Engineering Contradiction:
Improvethermal conductivityVSAvoidmechanical properties
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent optimizes the filler loading concentration within specific ranges (4 to 49.95 wt%) to balance thermal conductivity enhancement with maintenance of mechanical properties and processability. By controlling filler size, shape, distribution, and surface treatment, along with adjusting polymer matrix composition (using polyamides including nylon 6, nylon 6,6, nylon 10,10, nylon 10,12, or nylon 12,12), the formulation achieves optimal thermal performance without compromising structural integrity or flow characteristics during molding.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions effectively enhance thermal conductivity and maintain mechanical properties, enabling efficient heat dissipation and robust plating performance in portable electronic devices, addressing the challenge of heat retention in miniaturized electronics.

Implementation Method 1

thermally conductive filler having a thermal conductivity greater than or equal to 50 W/mK

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

laser direct structuring additive; wherein a molded sample of the blended thermoplastic composition exhibits a plating index value of at least 0.4 when determined in accordance with ATSM B568

Methodology Applied
Scientific EffectLaser absorption: Absorption (EM radiation)

Data Source

PatentEP3004227B1Thermally conductive polymer compositions with laser direct structuring function
Publication Date: 2019.07.24 SABIC GLOBAL TECHNOLOGIES BV
  • EP3004227B1 patent drawing
  • EP3004227B1 patent drawing
  • EP3004227B1 patent drawing

AI summary

Disclosed herein are methods and compositions of blended polyamide compositions with improved thermal conductivity. The resulting blended polymer compositions, comprising one or more polyamide polymers, one or more thermally conductive fillers, and a laser direct structuring additive, wherein the blended polymer composition has improved thermal conductivity.