Thermally Strippable Coating via Decomposable Intermediate Layer

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Solution Overview

Problem

Current methods for removing coatings from substrates are economically, environmentally, and health-wise disadvantageous, as they often involve harmful chemicals, create hazardous waste, or are inefficient in recycling coated materials, especially in complex geometries and when trying to preserve the coating's value.

Innovation Solution

A composite component with a thermally decomposable intermediate layer containing substances like nitrocellulose or poly(alkylene carbonate) that, when heated, evolves gas to separate the coating from the substrate without leaving residues, using a process that maintains the coating's adhesion strength until thermal activation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If chemical strippers are used to remove coatings, then coating removal is achieved, but harmful chemicals are consumed and released

Engineering Contradiction:
Improvecoating removal capabilityVSAvoidharmful chemical consumption and release
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent replaces chemical stripping mechanisms with a thermal-mechanical system. A thermally decomposable intermediate layer is applied between the coating and substrate, then heated to decompose and generate gas bubbles that mechanically lift and remove the coating. This substitutes harmful chemical processes with thermal energy input and mechanical bubble expansion, eliminating the need for harmful chemical strippers while achieving effective coating removal.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces a thermally decomposable intermediate layer as a mediator between the coating and substrate. This intermediate layer serves as a temporary bonding agent that can be selectively decomposed by heat to generate gas bubbles, which then act as a lifting mechanism to separate the coating from the substrate. The intermediary layer enables controlled, residue-free removal without direct contact between harmful chemicals and the coating-substrate system.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If mechanical removal methods like grinding or sandblasting are used, then coating is removed, but fine plastic particles are produced requiring protective equipment

Engineering Contradiction:
Improvecoating removal capabilityVSAvoidfine plastic particles
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent replaces mechanical abrasion methods (grinding, sandblasting) with a thermal-decomposition-based separation mechanism. Instead of mechanically fracturing the coating into fine particles through abrasive contact, the system uses thermal energy to decompose an intermediate layer, generating gas bubbles that gently lift and remove the coating as intact layers or large flakes. This eliminates the generation of fine plastic particles and the associated health hazards requiring protective equipment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes phase transitions of the thermally decomposable intermediate layer. When heated, the intermediate layer undergoes thermal decomposition and phase change, evolving from a solid bonding layer to a gas-filled separation layer. This phase transition mechanism enables non-contact, residue-free coating removal without the mechanical fragmentation that characterizes grinding and sandblasting processes.

Inventive Principle:
Principle #36Phase transitions

3Ease of manufacture

If laser ablation is used to remove coatings, then coating removal is achieved, but particulate matter is produced that is critical to environment and health

Engineering Contradiction:
Improvecoating removal capabilityVSAvoidparticulate matter
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent replaces laser ablation's high-energy photon-matter interaction with a controlled thermal decomposition process. Instead of using intense laser energy to vaporize and fragment the coating into hazardous particulate matter, the system uses moderate heating to decompose a specially formulated intermediate layer. The resulting gas bubbles provide a gentle lifting action that removes the coating without fragmentation, eliminating the generation of harmful particulate matter while maintaining effective coating removal capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces a thermally decomposable intermediate layer as a mediator that absorbs and channels thermal energy in a controlled manner. This intermediate layer decomposes at a specific temperature range to generate gas bubbles, which then mechanically separate the coating from the substrate without direct thermal exposure or high-energy photon interaction. The intermediary mechanism prevents the formation of hazardous particulate matter that would otherwise result from direct laser ablation of the coating.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Productivity

If coatings are removed to enable recycling, then material recovery is possible, but the removed coatings cannot be used to preserve their value

Engineering Contradiction:
Improverecycling efficiencyVSAvoidcoating value preservation
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent applies the extraction principle by selectively removing only the thermally decomposable intermediate layer through thermal decomposition, while leaving the coating and substrate intact and separable. The intermediate layer is extracted as a decomposed residue-free layer, enabling the coating to be recovered in its original intact form. This selective extraction approach allows the valuable coating material to be reused or recycled without contamination or degradation, preserving its original value while enabling efficient recycling of the substrate.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent implements a discarding and recovering strategy where the thermally decomposable intermediate layer is deliberately discarded through controlled thermal decomposition, while the coating and substrate are recovered in their original intact forms. The intermediate layer serves as a sacrificial component that is discarded after serving its bonding function, enabling clean separation and recovery of the valuable coating and substrate materials for reuse or recycling, thereby preserving coating value while improving recycling efficiency.

Inventive Principle:
Principle #34Discarding and recovering

5Ease of manufacture

If an intermediate layer with thermally decomposable substances is used, then residue-free separation is achieved, but the adhesion must be maintained until thermal activation

Engineering Contradiction:
Improveseparation cleanlinessVSAvoidadhesion strength before activation
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent utilizes parameter changes, specifically temperature-dependent adhesion characteristics of the intermediate layer. The intermediate layer is formulated to exhibit strong adhesion to both coating and substrate at ambient and processing temperatures, ensuring reliable bonding during application and use. Upon thermal activation at a specific temperature range, the intermediate layer undergoes decomposition and parameter change, causing adhesion loss and enabling separation. This temperature-dependent parameter change allows the system to maintain strong adhesion when needed while enabling clean, residue-free separation when thermally activated.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies dynamics by designing the intermediate layer with dynamic adhesion properties that change in response to thermal stimulation. The intermediate layer transitions from a static, strongly adhesive state during normal conditions to a dynamic, decomposing state under thermal activation. This dynamic behavior enables the intermediate layer to provide reliable bonding during application and service, then automatically transition to a separation-enabled state when heated, achieving both strong initial adhesion and clean subsequent separation.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables environmentally friendly and residue-free separation of coatings from substrates, allowing for efficient recycling and reuse of materials, with harmless gas production and minimal equipment complexity, suitable for various geometries and material combinations.

Implementation Method 1

an intermediate layer is arranged between the coating and the surface, which intermediate layer contains one or more thermally decomposable substances that can be thermally decomposed with the evolution of gas

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentEP4461528A1Thermally strippable coating
Publication Date: 2024.11.13 ADLER WERK LACKFAB JOHANN BERGHOFER
  • EP4461528A1 patent drawingFigure 1~2
  • EP4461528A1 patent drawingFigure 3~4
  • EP4461528A1 patent drawingFigure 5

AI summary

The invention relates to a composite component comprising a substrate and a coating covering a surface of the substrate, wherein an intermediate layer containing a substance that can be thermally decomposed with gas evolution is arranged between the coating and the surface. The invention further relates to methods for applying and removing the coating, as well as a recycling process for the composite component.